A surprisingly stable S-nitrosothiol complex

In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully...

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Detalles Bibliográficos
Autores principales:	Perissinotti, Laura L., Estrin, Dario Ariel, Doctorovich, Fabio Ariel
Publicado:	2006
Materias:	s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v128_n8_p2512_Perissinotti http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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