A surprisingly stable S-nitrosothiol complex

In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully...

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Autores principales:	Perissinotti, Laura L., Estrin, Dario Ariel, Doctorovich, Fabio Ariel
Publicado:	2006
Materias:	s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v128_n8_p2512_Perissinotti http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00027863_v128_n8_p2512_Perissinotti
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spelling	paper:paper_00027863_v128_n8_p2512_Perissinotti2023-06-08T14:22:42Z A surprisingly stable S-nitrosothiol complex Perissinotti, Laura L. Estrin, Dario Ariel Doctorovich, Fabio Ariel s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully characterized by FTIR, 1H NMR, and ESI-MS. To our knowledge this is the first example of a coordinated S-nitrosothiol that has been isolated. Copyright © 2006 American Chemical Society. Fil:Perissinotti, L.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Estrin, D.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v128_n8_p2512_Perissinotti http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis
spellingShingle	s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis Perissinotti, Laura L. Estrin, Dario Ariel Doctorovich, Fabio Ariel A surprisingly stable S-nitrosothiol complex
topic_facet	s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis
description	In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully characterized by FTIR, 1H NMR, and ESI-MS. To our knowledge this is the first example of a coordinated S-nitrosothiol that has been isolated. Copyright © 2006 American Chemical Society.
author	Perissinotti, Laura L. Estrin, Dario Ariel Doctorovich, Fabio Ariel
author_facet	Perissinotti, Laura L. Estrin, Dario Ariel Doctorovich, Fabio Ariel
author_sort	Perissinotti, Laura L.
title	A surprisingly stable S-nitrosothiol complex
title_short	A surprisingly stable S-nitrosothiol complex
title_full	A surprisingly stable S-nitrosothiol complex
title_fullStr	A surprisingly stable S-nitrosothiol complex
title_full_unstemmed	A surprisingly stable S-nitrosothiol complex
title_sort	surprisingly stable s-nitrosothiol complex
publishDate	2006
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v128_n8_p2512_Perissinotti http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti
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A surprisingly stable S-nitrosothiol complex

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