Superacid mesoporous carbón base don sulfated Zr

In this brief communication we report the successful preparation of a promising material with acidic properties from starch-derived mesoporous carbon (SMC), functionalized with sulfated zirconia. The process of assembling P123, starch, zirconia and silicon produces ordered mesoporous carbon modified...

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Detalles Bibliográficos
Autores principales: Anunziata, Oscar A., Martínez, María Laura
Formato: Documento de conferencia publisherVersion
Lenguaje:Inglés
Publicado: 2022
Materias:
Mesoporous carbon
Sulfated/Zirconia-starch mesoporous Carbon
super-acid Catalyst
Acceso en línea:http://hdl.handle.net/20.500.12272/6946
Aporte de:
RIA - Repositorio Institucional Abierto (UTN) de Universidad Tecnológica Nacional
id I68-R174-20.500.12272-6946
record_format dspace
institution Universidad Tecnológica Nacional
institution_str I-68
repository_str R-174
collection RIA - Repositorio Institucional Abierto (UTN)
language Inglés
topic Mesoporous carbon
Sulfated/Zirconia-starch mesoporous Carbon
super-acid Catalyst
spellingShingle Mesoporous carbon
Sulfated/Zirconia-starch mesoporous Carbon
super-acid Catalyst
Anunziata, Oscar A.
Martínez, María Laura
Superacid mesoporous carbón base don sulfated Zr
topic_facet Mesoporous carbon
Sulfated/Zirconia-starch mesoporous Carbon
super-acid Catalyst
description In this brief communication we report the successful preparation of a promising material with acidic properties from starch-derived mesoporous carbon (SMC), functionalized with sulfated zirconia. The process of assembling P123, starch, zirconia and silicon produces ordered mesoporous carbon modified with Zr. Reaction time and temperature are essential to avoid the appearance of poorly assembled or unsightly structures, reducing the surface area and the size of the pores. Zr-SMC has a surface area of approximately 1300 m2 g-1, and the total pore volume of 0.94 cm3 g-1, composed mainly of mesopores with an average pore size of 3.5 nm. The composition of the surface and the chemical states of the elements did not reveal ZrO2 as isolated clusters. Through the thermodesorption of the pre-adsorbed ammonia in the sulfated Zr-SMC, the total ammonia retained is 1.80 mmol / g at high temperature, exhibiting medium to strong acidity.
format Documento de conferencia
publisherVersion
author Anunziata, Oscar A.
Martínez, María Laura
author_facet Anunziata, Oscar A.
Martínez, María Laura
author_sort Anunziata, Oscar A.
title Superacid mesoporous carbón base don sulfated Zr
title_short Superacid mesoporous carbón base don sulfated Zr
title_full Superacid mesoporous carbón base don sulfated Zr
title_fullStr Superacid mesoporous carbón base don sulfated Zr
title_full_unstemmed Superacid mesoporous carbón base don sulfated Zr
title_sort superacid mesoporous carbón base don sulfated zr
publishDate 2022
url http://hdl.handle.net/20.500.12272/6946
work_keys_str_mv AT anunziataoscara superacidmesoporouscarbonbasedonsulfatedzr
AT martinezmarialaura superacidmesoporouscarbonbasedonsulfatedzr
bdutipo_str Repositorios
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