Heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils

In this study, four heterogeneous enzymatic catalysts were synthesized: three from the immobilization of Pseudomonas fluorescens lipase (LPf) on SBA-15, Ca/SBA-15, and Na / SBA-15, and one using the one-step coprecipitation technique, called LOBE (Low Ordered Biosilicificated Enzyme). The physicoch...

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Autores principales:	Ferrero, Gabriel O., Vaschetto, Eliana, Sánchez Faba, Edgar M., Viale, Fabrizio E., Carrillo, Germán, Eimer, Griselda Alejandra
Formato:	Documento de conferencia publisherVersion
Lenguaje:	Inglés
Publicado:	2022
Materias:	Heterogeneous enzymatic catalysts Comparing efficiency Production of biodiesel Alternative oils
Acceso en línea:	http://hdl.handle.net/20.500.12272/6340
Aporte de:	RIA - Repositorio Institucional Abierto (UTN) de Universidad Tecnológica Nacional

id	I68-R174-20.500.12272-6340
record_format	dspace
institution	Universidad Tecnológica Nacional
institution_str	I-68
repository_str	R-174
collection	RIA - Repositorio Institucional Abierto (UTN)
language	Inglés
topic	Heterogeneous enzymatic catalysts Comparing efficiency Production of biodiesel Alternative oils
spellingShingle	Heterogeneous enzymatic catalysts Comparing efficiency Production of biodiesel Alternative oils Ferrero, Gabriel O. Vaschetto, Eliana Sánchez Faba, Edgar M. Viale, Fabrizio E. Carrillo, Germán Eimer, Griselda Alejandra Heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils
topic_facet	Heterogeneous enzymatic catalysts Comparing efficiency Production of biodiesel Alternative oils
description	In this study, four heterogeneous enzymatic catalysts were synthesized: three from the immobilization of Pseudomonas fluorescens lipase (LPf) on SBA-15, Ca/SBA-15, and Na / SBA-15, and one using the one-step coprecipitation technique, called LOBE (Low Ordered Biosilicificated Enzyme). The physicochemical properties of these materials were determined by small-angle X-ray scattering (SAXS) and Fourier Transform infrared spectroscopy (FT-IR). The biocatalysts activity was evaluated in the production of biodiesel with different oily raw materials. It was possible to infer from these results that besides enzyme-metal-support synergistic effect (LPf/Ca/SBA-15 or LPf/Na/SBA-15), confinement effects influence the substrates diffusion or mass transfer depending on the pore, channel, or cavity architecture, determining the catalytic efficiency. While the SBA-15 material presents one-dimensional channels, the LOBE biocatalyst has interconnected three-dimensional cavities that favor the mixing of reactant phases (oil alcohol) and interaction with active sites. This characteristic would increase the specific activity of the LOBE biocatalyst approximately five times concerning
format	Documento de conferencia publisherVersion
author	Ferrero, Gabriel O. Vaschetto, Eliana Sánchez Faba, Edgar M. Viale, Fabrizio E. Carrillo, Germán Eimer, Griselda Alejandra
author_facet	Ferrero, Gabriel O. Vaschetto, Eliana Sánchez Faba, Edgar M. Viale, Fabrizio E. Carrillo, Germán Eimer, Griselda Alejandra
author_sort	Ferrero, Gabriel O.
title	Heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils
title_short	Heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils
title_full	Heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils
title_fullStr	Heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils
title_full_unstemmed	Heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils
title_sort	heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils
publishDate	2022
url	http://hdl.handle.net/20.500.12272/6340
work_keys_str_mv	AT ferrerogabrielo heterogeneousenzymaticcatalystscomparingtheirefficiencyintheproductionofbiodieselfromalternativeoils AT vaschettoeliana heterogeneousenzymaticcatalystscomparingtheirefficiencyintheproductionofbiodieselfromalternativeoils AT sanchezfabaedgarm heterogeneousenzymaticcatalystscomparingtheirefficiencyintheproductionofbiodieselfromalternativeoils AT vialefabrizioe heterogeneousenzymaticcatalystscomparingtheirefficiencyintheproductionofbiodieselfromalternativeoils AT carrillogerman heterogeneousenzymaticcatalystscomparingtheirefficiencyintheproductionofbiodieselfromalternativeoils AT eimergriseldaalejandra heterogeneousenzymaticcatalystscomparingtheirefficiencyintheproductionofbiodieselfromalternativeoils
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Heterogeneous enzymatic catalysts: comparing their efficiency in the production of biodiesel from alternative oils

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