Synthetic Organometallic Radical Chemistry in Water

Several organic radical transformations in aqueous media using organometallic chemistry are presented. Group XIV-elements, such as Si and Ge, and Sn-centered radicals make use of novel methodologies in water which employ both hydrophilic and lipophilic substrates without the requirements of surfacta...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autor principal:	Postigo, Al
Formato:	Artículo
Lenguaje:	Inglés
Publicado:	Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales. Investigación 2015
Materias:	Ciencias exactas Ingeniería Química Estudios químicos Radicales orgánicos Química organometálica Transformaciones orgánicas Química orgánica Medios acuosos Exact sciences Engineering Chemistry Chemical studies Organic radicals Organometallic chemistry Organic transformations Organic chemistry Aqueous environment
Acceso en línea:	http://repositorio.ub.edu.ar/handle/123456789/4844
Aporte de:	Repositorio Institucional - Universidad de Belgrano (UB) de Universidad de Belgrano

id	I36-R142-123456789-4844
record_format	dspace
institution	Universidad de Belgrano
institution_str	I-36
repository_str	R-142
collection	Repositorio Institucional - Universidad de Belgrano (UB)
language	Inglés
topic	Ciencias exactas Ingeniería Química Estudios químicos Radicales orgánicos Química organometálica Transformaciones orgánicas Química orgánica Medios acuosos Exact sciences Engineering Chemistry Chemical studies Organic radicals Organometallic chemistry Organic transformations Organic chemistry Aqueous environment
spellingShingle	Ciencias exactas Ingeniería Química Estudios químicos Radicales orgánicos Química organometálica Transformaciones orgánicas Química orgánica Medios acuosos Exact sciences Engineering Chemistry Chemical studies Organic radicals Organometallic chemistry Organic transformations Organic chemistry Aqueous environment Postigo, Al Synthetic Organometallic Radical Chemistry in Water
topic_facet	Ciencias exactas Ingeniería Química Estudios químicos Radicales orgánicos Química organometálica Transformaciones orgánicas Química orgánica Medios acuosos Exact sciences Engineering Chemistry Chemical studies Organic radicals Organometallic chemistry Organic transformations Organic chemistry Aqueous environment
description	Several organic radical transformations in aqueous media using organometallic chemistry are presented. Group XIV-elements, such as Si and Ge, and Sn-centered radicals make use of novel methodologies in water which employ both hydrophilic and lipophilic substrates without the requirements of surfactants. Different radical initiation techniques that account for effective initiation of the radical chain reactions in aqueous media are also described, such as the thermal decomposition of azo compounds, the direct photolysis (in the absence of an organic peroxide or other photolytic radical promoter) of silanes, dioxygen initiation techniques, and radical initiation in the absence of solvent, and in the presence of adventitious oxygen. Hydrometallation of multiple bonds with (Me3Si)3SiH and germane analogs in water are also described with the above mentioned initiating techniques, under solvent-free conditions, and performed in continuous flow microreactors. The use of other metal-centered radicals that promote synthetically useful organic transformations in water, such as Mg, Mn, and Zn, is presented. These transformations encompass simple organohalide reductions, and several types of carbon-carbon bond forming reactions, demonstrating the wide scope of organometallic radical chemistry in water for accomplishing organic transformations. Group XIII- centered radicals are also shown to be excellent mediators for organic radical reactions in water, such as Barbier-type alkylations and allylations of carbonyl compounds.
format	Article
author	Postigo, Al
author_facet	Postigo, Al
author_sort	Postigo, Al
title	Synthetic Organometallic Radical Chemistry in Water
title_short	Synthetic Organometallic Radical Chemistry in Water
title_full	Synthetic Organometallic Radical Chemistry in Water
title_fullStr	Synthetic Organometallic Radical Chemistry in Water
title_full_unstemmed	Synthetic Organometallic Radical Chemistry in Water
title_sort	synthetic organometallic radical chemistry in water
publisher	Universidad de Belgrano. Facultad de Ciencias Exactas y Naturales. Investigación
publishDate	2015
url	http://repositorio.ub.edu.ar/handle/123456789/4844
work_keys_str_mv	AT postigoal syntheticorganometallicradicalchemistryinwater
bdutipo_str	Repositorios
_version_	1764820529281236993

Synthetic Organometallic Radical Chemistry in Water

Ejemplares similares