Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step

The classical radical-based hydrosilylation reaction of organic compounds bearing C−C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solvent-soluble and water-soluble substrates. Different initiation methods to accomplish the radical-indu...

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Autores principales: Postigo, Al, Kopsov, Sergey, Zlotsky, Simon S., Ferreri, Carla, Chatgilialoglu, Chryssostomos
Formato: Artículo
Lenguaje:Inglés
Publicado: Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación 2014
Materias:
Hydrosilylation
Multiple Bonds
Radical Initiation Step
hidrosililación
Iniciación por radicales Paso
Enlaces múltiples
Acceso en línea:http://repositorio.ub.edu.ar/handle/123456789/2726
Aporte de:
Repositorio Institucional - Universidad de Belgrano (UB) de Universidad de Belgrano
id I36-R142-123456789-2726
record_format dspace
institution Universidad de Belgrano
institution_str I-36
repository_str R-142
collection Repositorio Institucional - Universidad de Belgrano (UB)
language Inglés
topic Hydrosilylation
Multiple Bonds
Radical Initiation Step
hidrosililación
Iniciación por radicales Paso
Enlaces múltiples
spellingShingle Hydrosilylation
Multiple Bonds
Radical Initiation Step
hidrosililación
Iniciación por radicales Paso
Enlaces múltiples
Postigo, Al
Kopsov, Sergey
Zlotsky, Simon S.
Ferreri, Carla
Chatgilialoglu, Chryssostomos
Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
topic_facet Hydrosilylation
Multiple Bonds
Radical Initiation Step
hidrosililación
Iniciación por radicales Paso
Enlaces múltiples
description The classical radical-based hydrosilylation reaction of organic compounds bearing C−C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solvent-soluble and water-soluble substrates. Different initiation methods to accomplish the radical-induced hydrosilylation reaction of C−C multiple bonds in water with (Me3Si)3SiH are presented. In the thermal decomposition of azo compounds, the system comprising substrate, silane, and azo-initiator (ACCN) mixed in aqueous medium at 100 °C worked well for both hydrophilic and hydrophobic substrates, with the only variation that the amphiphilic thiol HOCH2CH2SH was also needed in the case of the water-soluble compounds.
format Article
author Postigo, Al
Kopsov, Sergey
Zlotsky, Simon S.
Ferreri, Carla
Chatgilialoglu, Chryssostomos
author_facet Postigo, Al
Kopsov, Sergey
Zlotsky, Simon S.
Ferreri, Carla
Chatgilialoglu, Chryssostomos
author_sort Postigo, Al
title Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
title_short Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
title_full Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
title_fullStr Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
title_full_unstemmed Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
title_sort hydrosilylation of c−c multiple bonds using (me3si)3sih in water. comparative study of the radical initiation step
publisher Universidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación
publishDate 2014
url http://repositorio.ub.edu.ar/handle/123456789/2726
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