N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds

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The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinate...

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Autores principales:	Suarez, S.A., Foi, A., Eady, S., Larsen, A., Doctorovich, F.
Formato:	Artículo publishedVersion
Publicado:	2011
Materias:	Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_01082701_v67_n10_po417_Suarez_oai
Aporte de:	Repositorio Digital de la Universidad de Buenos Aires (UBA) de Universidad de Buenos Aires

id	I28-R145-paper_01082701_v67_n10_po417_Suarez_oai
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spelling	I28-R145-paper_01082701_v67_n10_po417_Suarez_oai2020-10-19 Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F. 2011 The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography. Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. application/pdf http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar Acta Crystallogr Sect C Cryst Struct Commun 2011;67(10):o417-o420 Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_01082701_v67_n10_po417_Suarez_oai
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-145
collection	Repositorio Digital de la Universidad de Buenos Aires (UBA)
topic	Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions
spellingShingle	Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F. N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
topic_facet	Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions
description	The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.
format	Artículo Artículo publishedVersion
author	Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F.
author_facet	Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F.
author_sort	Suarez, S.A.
title	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_short	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_full	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_fullStr	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_full_unstemmed	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_sort	n-butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
publishDate	2011
url	http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez http://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_01082701_v67_n10_po417_Suarez_oai
work_keys_str_mv	AT suarezsa nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT foia nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT eadys nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT larsena nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT doctorovichf nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds
_version_	1766026662933168128

N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds

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