A kinetic and mechanistic study on the thermal decomposition reactions of cis- and trans- fused 1,2,4-trioxanes

The kinetics of the thermal decomposition reactions of artemisinine (1), a cis-fused 1,2,4-trioxane, and trans-3,3dimethyl-1,2,4-trioxane (6) in solutions of benzene, toluene, and methanol in sealed tubes were compared at temperatures between 100.1° and 171.4 °C. Pseudo first-order rate constant val...

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Detalles Bibliográficos
Autores principales: Cafferata, Lázaro F. R., Jeandupeax, Rene, Romanelli, Gustavo Pablo, Mateo, Carmen Margarita, Jefford, Charles W.
Formato: Articulo
Lenguaje:Inglés
Publicado: 2003
Materias:
Química
Cis- and trans- fused 1,2,4-trioxanes
Artemisinine
Thermolysis
Reactions kinetics
Artemisinina
Termófisis
Cinética de reacción
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/98261
https://ri.conicet.gov.ar/11336/65056
https://dialnet.unirioja.es/servlet/articulo?codigo=2642748
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata

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