Metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of...

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Autores principales: Rafti, Matías, Allegretto, Juan Alejandro, Segovia, Gustavo M., Tuninetti, Jimena Soledad, Giussi, Juan Martín, Bindini, Elisa, Azzaroni, Omar
Formato: Articulo Preprint
Lenguaje:Inglés
Publicado: 2017
Materias:
Química
Metal organic frameworks
Polymer brushes
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/96094
https://ri.conicet.gov.ar/11336/63915
https://pubs.rsc.org/en/Content/ArticleLanding/2017/QM/C7QM00235A
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-96094
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Metal organic frameworks
Polymer brushes
spellingShingle Química
Metal organic frameworks
Polymer brushes
Rafti, Matías
Allegretto, Juan Alejandro
Segovia, Gustavo M.
Tuninetti, Jimena Soledad
Giussi, Juan Martín
Bindini, Elisa
Azzaroni, Omar
Metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
topic_facet Química
Metal organic frameworks
Polymer brushes
description We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of nucleation sites in the primer.
format Articulo
Preprint
author Rafti, Matías
Allegretto, Juan Alejandro
Segovia, Gustavo M.
Tuninetti, Jimena Soledad
Giussi, Juan Martín
Bindini, Elisa
Azzaroni, Omar
author_facet Rafti, Matías
Allegretto, Juan Alejandro
Segovia, Gustavo M.
Tuninetti, Jimena Soledad
Giussi, Juan Martín
Bindini, Elisa
Azzaroni, Omar
author_sort Rafti, Matías
title Metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
title_short Metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
title_full Metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
title_fullStr Metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
title_full_unstemmed Metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
title_sort metal-organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
publishDate 2017
url http://sedici.unlp.edu.ar/handle/10915/96094
https://ri.conicet.gov.ar/11336/63915
https://pubs.rsc.org/en/Content/ArticleLanding/2017/QM/C7QM00235A
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