Synthesis of MnFeO<sub>3</sub> from the oxidate thermal decomposition of Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O

On the basis of previous studies about the pentacyanonitrosylmetallates whose thermal decomposition generates different type of oxides, the Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O was used as raw material to give FeMnO<sub>3</sub>. The decomposition was studied b...

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Detalles Bibliográficos
Autores principales: Lick, Ileana Daniela, Soria, Delia Beatriz
Formato: Articulo
Lenguaje:Inglés
Publicado: 2009
Materias:
Ciencias Exactas
Química
Pentacyanonitrosylmetallates
Bixbyite
Thermal decomposition
Spinel
Pentacianonitrosilmetalatos
Espinela
Bixbyta
Descomposición térmica
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/95868
https://ri.conicet.gov.ar/11336/21777
http://aqa.org.ar/images/anales/pdf9701/9701art10.pdf
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-95868
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Pentacyanonitrosylmetallates
Bixbyite
Thermal decomposition
Spinel
Pentacianonitrosilmetalatos
Espinela
Bixbyta
Descomposición térmica
spellingShingle Ciencias Exactas
Química
Pentacyanonitrosylmetallates
Bixbyite
Thermal decomposition
Spinel
Pentacianonitrosilmetalatos
Espinela
Bixbyta
Descomposición térmica
Lick, Ileana Daniela
Soria, Delia Beatriz
Synthesis of MnFeO<sub>3</sub> from the oxidate thermal decomposition of Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O
topic_facet Ciencias Exactas
Química
Pentacyanonitrosylmetallates
Bixbyite
Thermal decomposition
Spinel
Pentacianonitrosilmetalatos
Espinela
Bixbyta
Descomposición térmica
description On the basis of previous studies about the pentacyanonitrosylmetallates whose thermal decomposition generates different type of oxides, the Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O was used as raw material to give FeMnO<sub>3</sub>. The decomposition was studied by Thermogravimetric (TGA-DTG) and Differential Thermal Analysis (DTA) under air atmosphere, between room temperature and 1200°C. IR spectroscopy and XRPD, refined by Rietveld analysis, were used to follow the process. The XRPD of the sample heated at different temperatures showed the following sequence: MnFe<sub>2</sub>O<sub>4</sub> and (Mn,Fe)<sub>2</sub>O<sub>3</sub> disordered bixbyte phases, until arriving to the final product, MnFeO<sub>3</sub>. Temperature programmed reduction (TPR) and EDS-EDAX analyses were used for the characterization, as well.
format Articulo
Articulo
author Lick, Ileana Daniela
Soria, Delia Beatriz
author_facet Lick, Ileana Daniela
Soria, Delia Beatriz
author_sort Lick, Ileana Daniela
title Synthesis of MnFeO<sub>3</sub> from the oxidate thermal decomposition of Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O
title_short Synthesis of MnFeO<sub>3</sub> from the oxidate thermal decomposition of Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O
title_full Synthesis of MnFeO<sub>3</sub> from the oxidate thermal decomposition of Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O
title_fullStr Synthesis of MnFeO<sub>3</sub> from the oxidate thermal decomposition of Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O
title_full_unstemmed Synthesis of MnFeO<sub>3</sub> from the oxidate thermal decomposition of Mn[Fe(CN)<sub>5</sub>NO]·2H<sub>2</sub>O
title_sort synthesis of mnfeo<sub>3</sub> from the oxidate thermal decomposition of mn[fe(cn)<sub>5</sub>no]·2h<sub>2</sub>o
publishDate 2009
url http://sedici.unlp.edu.ar/handle/10915/95868
https://ri.conicet.gov.ar/11336/21777
http://aqa.org.ar/images/anales/pdf9701/9701art10.pdf
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AT soriadeliabeatriz synthesisofmnfeosub3subfromtheoxidatethermaldecompositionofmnfecnsub5subno2hsub2subo
bdutipo_str Repositorios
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