Formulation and assessment of Wash-Primer containing lanthanum tannate for steel temporary protection

Tannins are polyphenols synthesized by plants and useful for the coating industry as corrosion inhibitors. In addition, lanthanum salts have a great inhibitory effect on steel corrosion. The aim of this study was to obtain lanthanum ‘‘tannate’’ with adequate solubility to be incorporated as the corr...

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Detalles Bibliográficos
Autores principales: D'Alessandro, Oriana, Selmi, Gonzalo, Deyá, Marta Cecilia, Di Sarli, Alejandro Ramón, Romagnoli, Roberto
Formato: Articulo
Lenguaje:Inglés
Publicado: 2018
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/94935
Aporte de:
id I19-R120-10915-94935
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ingeniería Química
Coatings and paints
Corrosion
Electrochemical impedance spectroscopy
Lanthanum
Tannins
spellingShingle Ingeniería Química
Coatings and paints
Corrosion
Electrochemical impedance spectroscopy
Lanthanum
Tannins
D'Alessandro, Oriana
Selmi, Gonzalo
Deyá, Marta Cecilia
Di Sarli, Alejandro Ramón
Romagnoli, Roberto
Formulation and assessment of Wash-Primer containing lanthanum tannate for steel temporary protection
topic_facet Ingeniería Química
Coatings and paints
Corrosion
Electrochemical impedance spectroscopy
Lanthanum
Tannins
description Tannins are polyphenols synthesized by plants and useful for the coating industry as corrosion inhibitors. In addition, lanthanum salts have a great inhibitory effect on steel corrosion. The aim of this study was to obtain lanthanum ‘‘tannate’’ with adequate solubility to be incorporated as the corrosion inhibitor in a wash-primer. The ‘‘tannate’’ was obtained from commercial ‘‘Quebracho’’ tannin and 0.1 M La(NO3)3. The soluble tannin was determined by the Folin–Denis reagent, while the concentration of Lanthanum was obtained by a gravimetric procedure. The protective action of ‘‘tannate’’ on SAE 1010 steel was evaluated by linear polarization curves and corrosion potential measurements. Lanthanum ‘‘tannate’’ was incorporated in a wash-primer formulation and tested by corrosion potential and ionic resistance measurements. The corrosion rate was also determined by the polarization resistance technique. Besides, the primer was incorporated in an alkyd paint system and its anticorrosion performance assessed in the salt spray cabinet and by electrochemical impedance spectroscopy. Results showed that lanthanum ‘‘tannate’’ primer inhibits the development of deleterious iron oxyhydroxides on the steel substrate and incorporated into a paint system had a similar behavior to the primer formulated with zinc tetroxychromate.
format Articulo
Articulo
author D'Alessandro, Oriana
Selmi, Gonzalo
Deyá, Marta Cecilia
Di Sarli, Alejandro Ramón
Romagnoli, Roberto
author_facet D'Alessandro, Oriana
Selmi, Gonzalo
Deyá, Marta Cecilia
Di Sarli, Alejandro Ramón
Romagnoli, Roberto
author_sort D'Alessandro, Oriana
title Formulation and assessment of Wash-Primer containing lanthanum tannate for steel temporary protection
title_short Formulation and assessment of Wash-Primer containing lanthanum tannate for steel temporary protection
title_full Formulation and assessment of Wash-Primer containing lanthanum tannate for steel temporary protection
title_fullStr Formulation and assessment of Wash-Primer containing lanthanum tannate for steel temporary protection
title_full_unstemmed Formulation and assessment of Wash-Primer containing lanthanum tannate for steel temporary protection
title_sort formulation and assessment of wash-primer containing lanthanum tannate for steel temporary protection
publishDate 2018
url http://sedici.unlp.edu.ar/handle/10915/94935
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