Self-lubricating Cu-MWCNT coatings deposited from an ecofriendly glutamate-based electrolyte

Self-lubricating coatings have been studied for a long time due to their convenience compared to systems which need periodic lubrication. For this reason, Cu-CNT composite coatings with high wear resistance and low coefficient of friction were obtained by electrodeposition from an ecofriendly alkaline...

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Autores principales: Bengoa, Leandro Nicolás, Seré, Pablo Ricardo, Pary, Paola, Conconi, María Susana, Folgueiras, José, Morel, Eneas, Torga, Jorge, Egli, Walter Alfredo
Formato: Articulo
Lenguaje:Inglés
Publicado: 2020
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/92291
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id I19-R120-10915-92291
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ingeniería
Copper
Carbon nanotubes
Composite
Friction
Tribology
spellingShingle Ingeniería
Copper
Carbon nanotubes
Composite
Friction
Tribology
Bengoa, Leandro Nicolás
Seré, Pablo Ricardo
Pary, Paola
Conconi, María Susana
Folgueiras, José
Morel, Eneas
Torga, Jorge
Egli, Walter Alfredo
Self-lubricating Cu-MWCNT coatings deposited from an ecofriendly glutamate-based electrolyte
topic_facet Ingeniería
Copper
Carbon nanotubes
Composite
Friction
Tribology
description Self-lubricating coatings have been studied for a long time due to their convenience compared to systems which need periodic lubrication. For this reason, Cu-CNT composite coatings with high wear resistance and low coefficient of friction were obtained by electrodeposition from an ecofriendly alkaline glutamate-based electrolyte. Deposition experiments were performed at various experimental conditions in the presence of lowfrequency ultrasound agitation to ensure particle dispersion and enhance their incorporation in the Cu matrix. Moreover, the effect of 2-Butyne-1,4-diol (an additive use in glutamate-based formulations) on coatings mechanical and tribological properties was assessed. Both pure Cu and Cu-CNT were obtained under all the experimental conditions considered and later characterized by SEM and XRD. Finally, pin-on disk tests were performed to estimate the coefficient of friction and determine the wear resistance. The results showed that incorporation of CNT to the copper matrix led to an improvement of the tribological performance of pure Cu, regardless of deposition parameters. Furthermore, it was found that 2-Butyne-1,4-diol had a strong influence on deposit microhardness and tribological performance, as a result of the changes in microstructure induced by this additive which promoted the development of a (111) texture. Likewise, the incorporation of particles to the Cu matrix promoted changes in surface morphology as well as in the preferred crystalline orientation, promoting crystal growth along the [311] direction. The results indicate that this simple and cheap methodology is suitable for fabrication of self-lubricating coatings.
format Articulo
Articulo
author Bengoa, Leandro Nicolás
Seré, Pablo Ricardo
Pary, Paola
Conconi, María Susana
Folgueiras, José
Morel, Eneas
Torga, Jorge
Egli, Walter Alfredo
author_facet Bengoa, Leandro Nicolás
Seré, Pablo Ricardo
Pary, Paola
Conconi, María Susana
Folgueiras, José
Morel, Eneas
Torga, Jorge
Egli, Walter Alfredo
author_sort Bengoa, Leandro Nicolás
title Self-lubricating Cu-MWCNT coatings deposited from an ecofriendly glutamate-based electrolyte
title_short Self-lubricating Cu-MWCNT coatings deposited from an ecofriendly glutamate-based electrolyte
title_full Self-lubricating Cu-MWCNT coatings deposited from an ecofriendly glutamate-based electrolyte
title_fullStr Self-lubricating Cu-MWCNT coatings deposited from an ecofriendly glutamate-based electrolyte
title_full_unstemmed Self-lubricating Cu-MWCNT coatings deposited from an ecofriendly glutamate-based electrolyte
title_sort self-lubricating cu-mwcnt coatings deposited from an ecofriendly glutamate-based electrolyte
publishDate 2020
url http://sedici.unlp.edu.ar/handle/10915/92291
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