Synthesis and characterization of ammonium acesulfamate

Ammonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods....

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Autores principales: Echeverría, Gustavo Alberto, Piro, Oscar Enrique, Parajón Costa, Beatriz S., Barán, Enrique José
Formato: Articulo
Lenguaje:Inglés
Publicado: 2014
Materias:
Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/85161
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-85161
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis
spellingShingle Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Parajón Costa, Beatriz S.
Barán, Enrique José
Synthesis and characterization of ammonium acesulfamate
topic_facet Química
Ammonium Acesulfamate
Crystal Structure
FTIR Spectra
Synthesis
description Ammonium acesulfamate, (NH4)C4H4NO 4S, was prepared by the reaction of acesulfamic acid and ammonium carbonate in aqueous solution, and characterized by elemental analysis and 1H and 13C NMR spectroscopy. Its crystal and molecular structure was determined by single-crystal X-ray diffraction methods. The substance crystallizes in the orthorhombic space group Pnma with Z = 4 molecules per unit cell. The NH4 + ion generates medium to strong hydrogen bonds with the carbonylic oxygen, the iminic nitrogen and the sulfonyl oxygen atoms of the acesulfamate anion. The FTIR spectrum of the compound was also recorded and is briefly discussed.
format Articulo
Articulo
author Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Parajón Costa, Beatriz S.
Barán, Enrique José
author_facet Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Parajón Costa, Beatriz S.
Barán, Enrique José
author_sort Echeverría, Gustavo Alberto
title Synthesis and characterization of ammonium acesulfamate
title_short Synthesis and characterization of ammonium acesulfamate
title_full Synthesis and characterization of ammonium acesulfamate
title_fullStr Synthesis and characterization of ammonium acesulfamate
title_full_unstemmed Synthesis and characterization of ammonium acesulfamate
title_sort synthesis and characterization of ammonium acesulfamate
publishDate 2014
url http://sedici.unlp.edu.ar/handle/10915/85161
work_keys_str_mv AT echeverriagustavoalberto synthesisandcharacterizationofammoniumacesulfamate
AT pirooscarenrique synthesisandcharacterizationofammoniumacesulfamate
AT parajoncostabeatrizs synthesisandcharacterizationofammoniumacesulfamate
AT baranenriquejose synthesisandcharacterizationofammoniumacesulfamate
bdutipo_str Repositorios
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