Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
The crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially c...
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| Autores principales: | , , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2011
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/84269 |
| Aporte de: |
| Sumario: | The crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially coordinated to the oxo group and equatorially to two hydroxylamido groups in a side-on fashion. The fifth equatorial binding site and the other apical position are occupied by an N and an O atom, respectively, from the methioninate anion acting as a bidentate ligand. |
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