Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O

The crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially c...

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Autores principales: Piro, Oscar Enrique, Echeverría, Gustavo Alberto, Arrambide, Gabriel, Gambino, Dinorah, Barán, Enrique José
Formato: Articulo
Lenguaje:Inglés
Publicado: 2011
Materias:
Química
Amino Acid Complex
Crystal Structure
Hydroxylamido Complex
Oxovanadium(V)Complex
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/84269
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-84269
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Amino Acid Complex
Crystal Structure
Hydroxylamido Complex
Oxovanadium(V)Complex
spellingShingle Química
Amino Acid Complex
Crystal Structure
Hydroxylamido Complex
Oxovanadium(V)Complex
Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Arrambide, Gabriel
Gambino, Dinorah
Barán, Enrique José
Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
topic_facet Química
Amino Acid Complex
Crystal Structure
Hydroxylamido Complex
Oxovanadium(V)Complex
description The crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially coordinated to the oxo group and equatorially to two hydroxylamido groups in a side-on fashion. The fifth equatorial binding site and the other apical position are occupied by an N and an O atom, respectively, from the methioninate anion acting as a bidentate ligand.
format Articulo
Articulo
author Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Arrambide, Gabriel
Gambino, Dinorah
Barán, Enrique José
author_facet Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Arrambide, Gabriel
Gambino, Dinorah
Barán, Enrique José
author_sort Piro, Oscar Enrique
title Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_short Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_full Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_fullStr Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_full_unstemmed Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
title_sort crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(v) complex, [vo(nh<sub>2</sub>o)<sub>2</sub>(dl-methioninato)]·h<sub>2</sub>o
publishDate 2011
url http://sedici.unlp.edu.ar/handle/10915/84269
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