Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
A simple and efficient procedure has been developed for the preparation of aryl-14H-dibenzo[a,j]xanthenes by a one-pot condensation of 2-naphthol and aryl aldehydes, in the presence of mesoporous zirconia modified with tungstophosphoric acid (ZrTPA60BT100), to be used as a heterogeneous catalyst in...
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Autores principales: | , , , |
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Formato: | Articulo |
Lenguaje: | Inglés |
Publicado: |
2012
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/84004 |
Aporte de: |
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I19-R120-10915-84004 |
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record_format |
dspace |
institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Química 14-aryl-14H-dibenzo[a,j]xanthenes heterogeneous catalysts heteropolyacids mesoporous zirconia solvent-free synthesis |
spellingShingle |
Química 14-aryl-14H-dibenzo[a,j]xanthenes heterogeneous catalysts heteropolyacids mesoporous zirconia solvent-free synthesis Rivera Vélez, Toa Sumak Blanco, Mirta Noemí Pizzio, Luis René Romanelli, Gustavo Pablo Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
topic_facet |
Química 14-aryl-14H-dibenzo[a,j]xanthenes heterogeneous catalysts heteropolyacids mesoporous zirconia solvent-free synthesis |
description |
A simple and efficient procedure has been developed for the preparation of aryl-14H-dibenzo[a,j]xanthenes by a one-pot condensation of 2-naphthol and aryl aldehydes, in the presence of mesoporous zirconia modified with tungstophosphoric acid (ZrTPA60BT100), to be used as a heterogeneous catalyst in a solvent-free medium using conventional heating. The present approach offers the advantages of clean reaction, simple methodology, short reaction time, and high yield. The reaction work-up is very simple and the catalyst can be easily separated from the reaction mixture and reused several times in subsequent reactions without appreciable loss of the catalytic activity. |
format |
Articulo Articulo |
author |
Rivera Vélez, Toa Sumak Blanco, Mirta Noemí Pizzio, Luis René Romanelli, Gustavo Pablo |
author_facet |
Rivera Vélez, Toa Sumak Blanco, Mirta Noemí Pizzio, Luis René Romanelli, Gustavo Pablo |
author_sort |
Rivera Vélez, Toa Sumak |
title |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
title_short |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
title_full |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
title_fullStr |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
title_full_unstemmed |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
title_sort |
green catalytic synthesis of 14-aryl-14h-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
publishDate |
2012 |
url |
http://sedici.unlp.edu.ar/handle/10915/84004 |
work_keys_str_mv |
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bdutipo_str |
Repositorios |
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1764820488280866820 |