Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid

A simple and efficient procedure has been developed for the preparation of aryl-14H-dibenzo[a,j]xanthenes by a one-pot condensation of 2-naphthol and aryl aldehydes, in the presence of mesoporous zirconia modified with tungstophosphoric acid (ZrTPA60BT100), to be used as a heterogeneous catalyst in...

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Autores principales: Rivera Vélez, Toa Sumak, Blanco, Mirta Noemí, Pizzio, Luis René, Romanelli, Gustavo Pablo
Formato: Articulo
Lenguaje:Inglés
Publicado: 2012
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/84004
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id I19-R120-10915-84004
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
14-aryl-14H-dibenzo[a,j]xanthenes
heterogeneous catalysts
heteropolyacids
mesoporous zirconia
solvent-free synthesis
spellingShingle Química
14-aryl-14H-dibenzo[a,j]xanthenes
heterogeneous catalysts
heteropolyacids
mesoporous zirconia
solvent-free synthesis
Rivera Vélez, Toa Sumak
Blanco, Mirta Noemí
Pizzio, Luis René
Romanelli, Gustavo Pablo
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
topic_facet Química
14-aryl-14H-dibenzo[a,j]xanthenes
heterogeneous catalysts
heteropolyacids
mesoporous zirconia
solvent-free synthesis
description A simple and efficient procedure has been developed for the preparation of aryl-14H-dibenzo[a,j]xanthenes by a one-pot condensation of 2-naphthol and aryl aldehydes, in the presence of mesoporous zirconia modified with tungstophosphoric acid (ZrTPA60BT100), to be used as a heterogeneous catalyst in a solvent-free medium using conventional heating. The present approach offers the advantages of clean reaction, simple methodology, short reaction time, and high yield. The reaction work-up is very simple and the catalyst can be easily separated from the reaction mixture and reused several times in subsequent reactions without appreciable loss of the catalytic activity.
format Articulo
Articulo
author Rivera Vélez, Toa Sumak
Blanco, Mirta Noemí
Pizzio, Luis René
Romanelli, Gustavo Pablo
author_facet Rivera Vélez, Toa Sumak
Blanco, Mirta Noemí
Pizzio, Luis René
Romanelli, Gustavo Pablo
author_sort Rivera Vélez, Toa Sumak
title Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
title_short Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
title_full Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
title_fullStr Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
title_full_unstemmed Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
title_sort green catalytic synthesis of 14-aryl-14h-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
publishDate 2012
url http://sedici.unlp.edu.ar/handle/10915/84004
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