Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid
A simple and efficient procedure has been developed for the preparation of aryl-14H-dibenzo[a,j]xanthenes by a one-pot condensation of 2-naphthol and aryl aldehydes, in the presence of mesoporous zirconia modified with tungstophosphoric acid (ZrTPA60BT100), to be used as a heterogeneous catalyst in...
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| Autores principales: | , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2012
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| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/84004 |
| Aporte de: |
| id |
I19-R120-10915-84004 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Química 14-aryl-14H-dibenzo[a,j]xanthenes heterogeneous catalysts heteropolyacids mesoporous zirconia solvent-free synthesis |
| spellingShingle |
Química 14-aryl-14H-dibenzo[a,j]xanthenes heterogeneous catalysts heteropolyacids mesoporous zirconia solvent-free synthesis Rivera Vélez, Toa Sumak Blanco, Mirta Noemí Pizzio, Luis René Romanelli, Gustavo Pablo Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
| topic_facet |
Química 14-aryl-14H-dibenzo[a,j]xanthenes heterogeneous catalysts heteropolyacids mesoporous zirconia solvent-free synthesis |
| description |
A simple and efficient procedure has been developed for the preparation of aryl-14H-dibenzo[a,j]xanthenes by a one-pot condensation of 2-naphthol and aryl aldehydes, in the presence of mesoporous zirconia modified with tungstophosphoric acid (ZrTPA60BT100), to be used as a heterogeneous catalyst in a solvent-free medium using conventional heating. The present approach offers the advantages of clean reaction, simple methodology, short reaction time, and high yield. The reaction work-up is very simple and the catalyst can be easily separated from the reaction mixture and reused several times in subsequent reactions without appreciable loss of the catalytic activity. |
| format |
Articulo Articulo |
| author |
Rivera Vélez, Toa Sumak Blanco, Mirta Noemí Pizzio, Luis René Romanelli, Gustavo Pablo |
| author_facet |
Rivera Vélez, Toa Sumak Blanco, Mirta Noemí Pizzio, Luis René Romanelli, Gustavo Pablo |
| author_sort |
Rivera Vélez, Toa Sumak |
| title |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
| title_short |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
| title_full |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
| title_fullStr |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
| title_full_unstemmed |
Green catalytic synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
| title_sort |
green catalytic synthesis of 14-aryl-14h-dibenzo[a,j]xanthenes using recyclable mesoporous zirconia modified with tungstophosphoric acid |
| publishDate |
2012 |
| url |
http://sedici.unlp.edu.ar/handle/10915/84004 |
| work_keys_str_mv |
AT riveraveleztoasumak greencatalyticsynthesisof14aryl14hdibenzoajxanthenesusingrecyclablemesoporouszirconiamodifiedwithtungstophosphoricacid AT blancomirtanoemi greencatalyticsynthesisof14aryl14hdibenzoajxanthenesusingrecyclablemesoporouszirconiamodifiedwithtungstophosphoricacid AT pizzioluisrene greencatalyticsynthesisof14aryl14hdibenzoajxanthenesusingrecyclablemesoporouszirconiamodifiedwithtungstophosphoricacid AT romanelligustavopablo greencatalyticsynthesisof14aryl14hdibenzoajxanthenesusingrecyclablemesoporouszirconiamodifiedwithtungstophosphoricacid |
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Repositorios |
| _version_ |
1764820488280866820 |