Voltammetric characterization of [ReO]3+ containing complexes
In the present work, the voltammetric profiles of Au-pc in 1 mM solutions of K[Re<SUP>V</SUP>OCl<SUB>2</SUB>(L)] (L = dianions of H<SUB>2</SUB>hida or H<SUB>2</SUB>eida; hida, n-(2,6-dimethylphenyl carbamoylmethyl)imino diacetic acid, and eida, 2,6-die...
| Autores principales: | , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2007
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/83370 |
| Aporte de: |
| id |
I19-R120-10915-83370 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ciencias Exactas solutions complexes rhenium |
| spellingShingle |
Ciencias Exactas solutions complexes rhenium Cerda, María Fernanda Kremer, Carlos Castro Luna, Ana María Méndez, Eduardo Voltammetric characterization of [ReO]3+ containing complexes |
| topic_facet |
Ciencias Exactas solutions complexes rhenium |
| description |
In the present work, the voltammetric profiles of Au-pc in 1 mM solutions of K[Re<SUP>V</SUP>OCl<SUB>2</SUB>(L)] (L = dianions of H<SUB>2</SUB>hida or H<SUB>2</SUB>eida; hida, n-(2,6-dimethylphenyl carbamoylmethyl)imino diacetic acid, and eida, 2,6-diethyl ida) complexes were evaluated. The obtained electrochemical response was the result of the contributions coming from the [ReO]<SUP>3+</SUP> <i>core</i> (E<SUB>pa</SUB> at ca. 0.2 V vs. Ag/AgNO<SUB>3</SUB>) and the carboxylic group of the ligand. There where also observed redox contributions ascribed to the presence of perrhenate coming from the decomposition of the complex with the lost of ligands, in agreement with the low stability of the studied complexes. copyright The Electrochemical Society. |
| format |
Articulo Articulo |
| author |
Cerda, María Fernanda Kremer, Carlos Castro Luna, Ana María Méndez, Eduardo |
| author_facet |
Cerda, María Fernanda Kremer, Carlos Castro Luna, Ana María Méndez, Eduardo |
| author_sort |
Cerda, María Fernanda |
| title |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_short |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_full |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_fullStr |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_full_unstemmed |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_sort |
voltammetric characterization of [reo]3+ containing complexes |
| publishDate |
2007 |
| url |
http://sedici.unlp.edu.ar/handle/10915/83370 |
| work_keys_str_mv |
AT cerdamariafernanda voltammetriccharacterizationofreo3containingcomplexes AT kremercarlos voltammetriccharacterizationofreo3containingcomplexes AT castrolunaanamaria voltammetriccharacterizationofreo3containingcomplexes AT mendezeduardo voltammetriccharacterizationofreo3containingcomplexes |
| bdutipo_str |
Repositorios |
| _version_ |
1764820488550350849 |