A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine

The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate...

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Detalles Bibliográficos
Autores principales: Barán, Enrique José, Piro, Oscar Enrique, Zinczuk, Juan
Formato: Articulo
Lenguaje:Inglés
Publicado: 2007
Materias:
Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/83080
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-83080
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct
spellingShingle Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct
Barán, Enrique José
Piro, Oscar Enrique
Zinczuk, Juan
A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
topic_facet Química
Crystallographic data
Hexamethylenediammonium bis(thiosaccharinate) dihydrate
IR spectra
Supramolecular adduct
description The crystal structure of hexamethylenediammonium bis(thiosaccharinate) dihydrate, [H3N-(CH2)6-NH3](tsac) 2 · 2 H2O (tsac = C7H4NO 2S2, the anion of thiosaccharin), was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/a with Z = 4. The thiosaccharinate moiety is planar and shows small but significant modifications in the bonding of the thioamide functional group as compared with the protonated neutral molecule. The ionic crystal is further stabilized by an extensive H-bonding network, which links the anions and cations into an infinite three-dimensional supramolecular assembly. The FTIR spectrum of the compound is briefly discussed in comparison with those of the neutral constituent molecules.
format Articulo
Articulo
author Barán, Enrique José
Piro, Oscar Enrique
Zinczuk, Juan
author_facet Barán, Enrique José
Piro, Oscar Enrique
Zinczuk, Juan
author_sort Barán, Enrique José
title A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_short A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_full A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_fullStr A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_full_unstemmed A new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
title_sort new supramolecular assembly obtained by reaction between thiosaccharin and hexamethylenediamine
publishDate 2007
url http://sedici.unlp.edu.ar/handle/10915/83080
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