Changes in the electrochemical response of noble metals produced by square-wave potential perturbations : A new technique for the preparation of reproducible electrode surfaces of interest in electrocatalysis
A square-wave potential anodizing procedure to obtain noble metal surfaces with both a controlled roughness and a reproducible electrochemical response is presented. The influence of the characteristics of the square-wave potential perturbation are systematically studied. The modification of the sur...
Guardado en:
| Autores principales: | , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1983
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/79603 |
| Aporte de: |
| id |
I19-R120-10915-79603 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ciencias Exactas Química Electroquímica Metal Electrodos electrocatalysis square-wave potential metales nobles noble metals |
| spellingShingle |
Ciencias Exactas Química Electroquímica Metal Electrodos electrocatalysis square-wave potential metales nobles noble metals Chialvo, Abel Cesar Triaca, Walter Enrique Arvia, Alejandro Jorge Changes in the electrochemical response of noble metals produced by square-wave potential perturbations : A new technique for the preparation of reproducible electrode surfaces of interest in electrocatalysis |
| topic_facet |
Ciencias Exactas Química Electroquímica Metal Electrodos electrocatalysis square-wave potential metales nobles noble metals |
| description |
A square-wave potential anodizing procedure to obtain noble metal surfaces with both a controlled roughness and a reproducible electrochemical response is presented. The influence of the characteristics of the square-wave potential perturbation are systematically studied. The modification of the surface takes place through the formation of a hydrated platinum oxide layer which is later electroreduced. The mechanism of growth of the hydrated oxide layer under both square-wave potential perturbation and potentiostatic conditions is critically discussed in terms of a complex sandwich-type structure. |
| format |
Articulo Articulo |
| author |
Chialvo, Abel Cesar Triaca, Walter Enrique Arvia, Alejandro Jorge |
| author_facet |
Chialvo, Abel Cesar Triaca, Walter Enrique Arvia, Alejandro Jorge |
| author_sort |
Chialvo, Abel Cesar |
| title |
Changes in the electrochemical response of noble metals produced by square-wave potential perturbations : A new technique for the preparation of reproducible electrode surfaces of interest in electrocatalysis |
| title_short |
Changes in the electrochemical response of noble metals produced by square-wave potential perturbations : A new technique for the preparation of reproducible electrode surfaces of interest in electrocatalysis |
| title_full |
Changes in the electrochemical response of noble metals produced by square-wave potential perturbations : A new technique for the preparation of reproducible electrode surfaces of interest in electrocatalysis |
| title_fullStr |
Changes in the electrochemical response of noble metals produced by square-wave potential perturbations : A new technique for the preparation of reproducible electrode surfaces of interest in electrocatalysis |
| title_full_unstemmed |
Changes in the electrochemical response of noble metals produced by square-wave potential perturbations : A new technique for the preparation of reproducible electrode surfaces of interest in electrocatalysis |
| title_sort |
changes in the electrochemical response of noble metals produced by square-wave potential perturbations : a new technique for the preparation of reproducible electrode surfaces of interest in electrocatalysis |
| publishDate |
1983 |
| url |
http://sedici.unlp.edu.ar/handle/10915/79603 |
| work_keys_str_mv |
AT chialvoabelcesar changesintheelectrochemicalresponseofnoblemetalsproducedbysquarewavepotentialperturbationsanewtechniqueforthepreparationofreproducibleelectrodesurfacesofinterestinelectrocatalysis AT triacawalterenrique changesintheelectrochemicalresponseofnoblemetalsproducedbysquarewavepotentialperturbationsanewtechniqueforthepreparationofreproducibleelectrodesurfacesofinterestinelectrocatalysis AT arviaalejandrojorge changesintheelectrochemicalresponseofnoblemetalsproducedbysquarewavepotentialperturbationsanewtechniqueforthepreparationofreproducibleelectrodesurfacesofinterestinelectrocatalysis |
| bdutipo_str |
Repositorios |
| _version_ |
1764820486932398080 |