Validation of an HPLC method for quantitative determination of benzocaine in PHBV-microparticles and PLA-nanoparticles

Benzocaine (BZC) is an ester-type local anesthetic used mainly in topical, dermal and mucosal formulations. The present work consists of the development and validation of analytical methodology for evaluation of benzocaine content in the micro and nanoparticles produced by biodegradable polymers (po...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Grillo, Renato, S. de Melo, Nathalie F., Araújo, Daniele R. de, Paula, Eneida de, Dias Filho, Newton L., Rosa, André H., Fraceto, Leonardo F.
Formato: Articulo
Lenguaje:Inglés
Publicado: 2009
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/7774
http://www.latamjpharm.org/trabajos/28/3/LAJOP_28_3_1_10_662Q8GBZMX.pdf
Aporte de:
id I19-R120-10915-7774
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Farmacia
Nanocápsulas
benzocaína; metodología analítica; micropartículas; nanopartículas; polímeros biodegradables
benzocaine; analytical methodology; microparticles; nanoparticles; biodegradable polymers
spellingShingle Farmacia
Nanocápsulas
benzocaína; metodología analítica; micropartículas; nanopartículas; polímeros biodegradables
benzocaine; analytical methodology; microparticles; nanoparticles; biodegradable polymers
Grillo, Renato
S. de Melo, Nathalie F.
Araújo, Daniele R. de
Paula, Eneida de
Dias Filho, Newton L.
Rosa, André H.
Fraceto, Leonardo F.
Validation of an HPLC method for quantitative determination of benzocaine in PHBV-microparticles and PLA-nanoparticles
topic_facet Farmacia
Nanocápsulas
benzocaína; metodología analítica; micropartículas; nanopartículas; polímeros biodegradables
benzocaine; analytical methodology; microparticles; nanoparticles; biodegradable polymers
description Benzocaine (BZC) is an ester-type local anesthetic used mainly in topical, dermal and mucosal formulations. The present work consists of the development and validation of analytical methodology for evaluation of benzocaine content in the micro and nanoparticles produced by biodegradable polymers (polyhydroxybutyrate-co-hydroxyvalerate and poly-(L-lactide) by HPLC. The validation was done using the reversed-phase C18 column, using a mobile phase consisting of acetonitrile/water 50:50 (v/v), flow rate of 1.5 mL/min and UV-vis detector at 285 nm. The results here obtained showed that the analytical methodology is accurate, reproducible, robust and linear over the molar range concentration of 10-100 μM of benzocaine. The limit of quantification and detection was 13.06 μM and 3.92 μM, respectively. The encapsulation efficiency of benzocaine in PHBV microspheres and PLA nanocapsule were 40% and 70%, respectively. The method developed was applied in the analysis of benzocaine in micro and nanoparticle systems and showed to be efficient, yielding good results. Here, this method was used to evaluate the encapsulation efficiency of benzocaine and will be used in next studies with different micro/nanoparticle formulations.
format Articulo
Articulo
author Grillo, Renato
S. de Melo, Nathalie F.
Araújo, Daniele R. de
Paula, Eneida de
Dias Filho, Newton L.
Rosa, André H.
Fraceto, Leonardo F.
author_facet Grillo, Renato
S. de Melo, Nathalie F.
Araújo, Daniele R. de
Paula, Eneida de
Dias Filho, Newton L.
Rosa, André H.
Fraceto, Leonardo F.
author_sort Grillo, Renato
title Validation of an HPLC method for quantitative determination of benzocaine in PHBV-microparticles and PLA-nanoparticles
title_short Validation of an HPLC method for quantitative determination of benzocaine in PHBV-microparticles and PLA-nanoparticles
title_full Validation of an HPLC method for quantitative determination of benzocaine in PHBV-microparticles and PLA-nanoparticles
title_fullStr Validation of an HPLC method for quantitative determination of benzocaine in PHBV-microparticles and PLA-nanoparticles
title_full_unstemmed Validation of an HPLC method for quantitative determination of benzocaine in PHBV-microparticles and PLA-nanoparticles
title_sort validation of an hplc method for quantitative determination of benzocaine in phbv-microparticles and pla-nanoparticles
publishDate 2009
url http://sedici.unlp.edu.ar/handle/10915/7774
http://www.latamjpharm.org/trabajos/28/3/LAJOP_28_3_1_10_662Q8GBZMX.pdf
work_keys_str_mv AT grillorenato validationofanhplcmethodforquantitativedeterminationofbenzocaineinphbvmicroparticlesandplananoparticles
AT sdemelonathalief validationofanhplcmethodforquantitativedeterminationofbenzocaineinphbvmicroparticlesandplananoparticles
AT araujodanielerde validationofanhplcmethodforquantitativedeterminationofbenzocaineinphbvmicroparticlesandplananoparticles
AT paulaeneidade validationofanhplcmethodforquantitativedeterminationofbenzocaineinphbvmicroparticlesandplananoparticles
AT diasfilhonewtonl validationofanhplcmethodforquantitativedeterminationofbenzocaineinphbvmicroparticlesandplananoparticles
AT rosaandreh validationofanhplcmethodforquantitativedeterminationofbenzocaineinphbvmicroparticlesandplananoparticles
AT fracetoleonardof validationofanhplcmethodforquantitativedeterminationofbenzocaineinphbvmicroparticlesandplananoparticles
bdutipo_str Repositorios
_version_ 1764820485046009857