A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O)

The acylation of alcohols, phenols, thiols, and amines with varied substitution using acid anhydrides is efficiently catalyzed by Wells-Dawson heteropoly acid (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O). React...

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Autores principales: Romanelli, Gustavo Pablo, Bennardi, Daniel Oscar, Autino, Juan Carlos, Baronetti, Graciela Teresita, Thomas, Horacio Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 2008
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/40111
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spelling I19-R120-10915-401112023-08-15T18:22:01Z http://sedici.unlp.edu.ar/handle/10915/40111 A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O) Romanelli, Gustavo Pablo Bennardi, Daniel Oscar Autino, Juan Carlos Baronetti, Graciela Teresita Thomas, Horacio Jorge 2008 2014-09-18T16:50:50Z en Ciencias Exactas Química acylation alcohols amines heteropolyacid phenols thiols Wells-Dawson catalyst The acylation of alcohols, phenols, thiols, and amines with varied substitution using acid anhydrides is efficiently catalyzed by Wells-Dawson heteropoly acid (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O). Reactions proceed with very good to excellent yield in air at room temperature, using toluene as solvent (40 examples). The bulk catalyst was easily reused without appreciable loss of its activity. Facultad de Ciencias Exactas Articulo Articulo http://creativecommons.org/licenses/by/3.0/ Creative Commons Attribution 3.0 Unported (CC BY 3.0) application/pdf 641-647
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
acylation
alcohols
amines
heteropolyacid
phenols
thiols
Wells-Dawson catalyst
spellingShingle Ciencias Exactas
Química
acylation
alcohols
amines
heteropolyacid
phenols
thiols
Wells-Dawson catalyst
Romanelli, Gustavo Pablo
Bennardi, Daniel Oscar
Autino, Juan Carlos
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O)
topic_facet Ciencias Exactas
Química
acylation
alcohols
amines
heteropolyacid
phenols
thiols
Wells-Dawson catalyst
description The acylation of alcohols, phenols, thiols, and amines with varied substitution using acid anhydrides is efficiently catalyzed by Wells-Dawson heteropoly acid (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O). Reactions proceed with very good to excellent yield in air at room temperature, using toluene as solvent (40 examples). The bulk catalyst was easily reused without appreciable loss of its activity.
format Articulo
Articulo
author Romanelli, Gustavo Pablo
Bennardi, Daniel Oscar
Autino, Juan Carlos
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
author_facet Romanelli, Gustavo Pablo
Bennardi, Daniel Oscar
Autino, Juan Carlos
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
author_sort Romanelli, Gustavo Pablo
title A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O)
title_short A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O)
title_full A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O)
title_fullStr A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O)
title_full_unstemmed A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H<SUB>6</SUB>P<SUB>2</SUB>W<SUB>18</SUB>O<SUB>62</SUB>·24 H<SUB>2</SUB>O)
title_sort simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (h<sub>6</sub>p<sub>2</sub>w<sub>18</sub>o<sub>62</sub>·24 h<sub>2</sub>o)
publishDate 2008
url http://sedici.unlp.edu.ar/handle/10915/40111
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