QSPR calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals

We report the results of a calculation of the normal boiling points of a representative set of 200 organic molecules through the application of QSPR theory. For this purpose we have used a particular set of flexible molecular descriptors, the so called Correlation Weighting of Atomic Orbitals with E...

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Autores principales: Pérez González, Maykel, Toropov, Andrey A., Duchowicz, Pablo Román, Castro, Eduardo A.
Formato: Articulo
Lenguaje:Inglés
Publicado: 2004
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/35121
http://www.mdpi.com/1420-3049/9/12/1019
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Sumario:We report the results of a calculation of the normal boiling points of a representative set of 200 organic molecules through the application of QSPR theory. For this purpose we have used a particular set of flexible molecular descriptors, the so called Correlation Weighting of Atomic Orbitals with Extended Connectivity of Zero- and First-Order Graphs of Atomic Orbitals. Although in general the results show suitable behavior to predict this physical chemistry property, the existence of some deviant behaviors points to a need to complement this index with some other sort of molecular descriptors. Some possible extensions of this study are discussed.