QSPR calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals

We report the results of a calculation of the normal boiling points of a representative set of 200 organic molecules through the application of QSPR theory. For this purpose we have used a particular set of flexible molecular descriptors, the so called Correlation Weighting of Atomic Orbitals with E...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Pérez González, Maykel, Toropov, Andrey A., Duchowicz, Pablo Román, Castro, Eduardo A.
Formato: Articulo
Lenguaje:Inglés
Publicado: 2004
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/35121
http://www.mdpi.com/1420-3049/9/12/1019
Aporte de:
id I19-R120-10915-35121
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Física
physical chemistry
boiling point
quantitative structure property relation
correlation weighting of atomic orbitals
flexible molecular descriptors
quantum theory
macrocyclic compounds
organic chemicals
regression analysis
transition temperature
spellingShingle Ciencias Exactas
Física
physical chemistry
boiling point
quantitative structure property relation
correlation weighting of atomic orbitals
flexible molecular descriptors
quantum theory
macrocyclic compounds
organic chemicals
regression analysis
transition temperature
Pérez González, Maykel
Toropov, Andrey A.
Duchowicz, Pablo Román
Castro, Eduardo A.
QSPR calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals
topic_facet Ciencias Exactas
Física
physical chemistry
boiling point
quantitative structure property relation
correlation weighting of atomic orbitals
flexible molecular descriptors
quantum theory
macrocyclic compounds
organic chemicals
regression analysis
transition temperature
description We report the results of a calculation of the normal boiling points of a representative set of 200 organic molecules through the application of QSPR theory. For this purpose we have used a particular set of flexible molecular descriptors, the so called Correlation Weighting of Atomic Orbitals with Extended Connectivity of Zero- and First-Order Graphs of Atomic Orbitals. Although in general the results show suitable behavior to predict this physical chemistry property, the existence of some deviant behaviors points to a need to complement this index with some other sort of molecular descriptors. Some possible extensions of this study are discussed.
format Articulo
Articulo
author Pérez González, Maykel
Toropov, Andrey A.
Duchowicz, Pablo Román
Castro, Eduardo A.
author_facet Pérez González, Maykel
Toropov, Andrey A.
Duchowicz, Pablo Román
Castro, Eduardo A.
author_sort Pérez González, Maykel
title QSPR calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals
title_short QSPR calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals
title_full QSPR calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals
title_fullStr QSPR calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals
title_full_unstemmed QSPR calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals
title_sort qspr calculation of normal boiling points of organic molecules based on the use of correlation weighting of atomic orbitals with extended connectivity of zero- and first-order graphs of atomic orbitals
publishDate 2004
url http://sedici.unlp.edu.ar/handle/10915/35121
http://www.mdpi.com/1420-3049/9/12/1019
work_keys_str_mv AT perezgonzalezmaykel qsprcalculationofnormalboilingpointsoforganicmoleculesbasedontheuseofcorrelationweightingofatomicorbitalswithextendedconnectivityofzeroandfirstordergraphsofatomicorbitals
AT toropovandreya qsprcalculationofnormalboilingpointsoforganicmoleculesbasedontheuseofcorrelationweightingofatomicorbitalswithextendedconnectivityofzeroandfirstordergraphsofatomicorbitals
AT duchowiczpabloroman qsprcalculationofnormalboilingpointsoforganicmoleculesbasedontheuseofcorrelationweightingofatomicorbitalswithextendedconnectivityofzeroandfirstordergraphsofatomicorbitals
AT castroeduardoa qsprcalculationofnormalboilingpointsoforganicmoleculesbasedontheuseofcorrelationweightingofatomicorbitalswithextendedconnectivityofzeroandfirstordergraphsofatomicorbitals
bdutipo_str Repositorios
_version_ 1764820470864019458