Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure

Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalys...

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Autores principales: Romanelli, Gustavo Pablo, Autino, Juan Carlos, Baronetti, Graciela Teresita, Thomas, Horacio Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 2001
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/35055
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spelling I19-R120-10915-350552023-08-15T18:13:02Z http://sedici.unlp.edu.ar/handle/10915/35055 Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure Romanelli, Gustavo Pablo Autino, Juan Carlos Baronetti, Graciela Teresita Thomas, Horacio Jorge 2001 2014-04-29T20:58:40Z en Ciencias Exactas Química heteropolyacids acid methoxymethyl ethers ester derivative phenols organic solvent phenol derivative protecting groups Well-Dawson catalyst silicon dioxide catalysis deprotection reaction Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalyst was easily recoverable and reusable. Facultad de Ciencias Exactas Articulo Articulo http://creativecommons.org/licenses/by/3.0/ Creative Commons Attribution 3.0 Unported (CC BY 3.0) application/pdf 1006-1011
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
heteropolyacids
acid
methoxymethyl ethers
ester derivative
phenols
organic solvent
phenol derivative
protecting groups
Well-Dawson catalyst
silicon dioxide
catalysis
deprotection reaction
spellingShingle Ciencias Exactas
Química
heteropolyacids
acid
methoxymethyl ethers
ester derivative
phenols
organic solvent
phenol derivative
protecting groups
Well-Dawson catalyst
silicon dioxide
catalysis
deprotection reaction
Romanelli, Gustavo Pablo
Autino, Juan Carlos
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
topic_facet Ciencias Exactas
Química
heteropolyacids
acid
methoxymethyl ethers
ester derivative
phenols
organic solvent
phenol derivative
protecting groups
Well-Dawson catalyst
silicon dioxide
catalysis
deprotection reaction
description Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalyst was easily recoverable and reusable.
format Articulo
Articulo
author Romanelli, Gustavo Pablo
Autino, Juan Carlos
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
author_facet Romanelli, Gustavo Pablo
Autino, Juan Carlos
Baronetti, Graciela Teresita
Thomas, Horacio Jorge
author_sort Romanelli, Gustavo Pablo
title Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_short Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_full Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_fullStr Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_full_unstemmed Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_sort efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with wells-dawson structure
publishDate 2001
url http://sedici.unlp.edu.ar/handle/10915/35055
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