Perfluoropropionic acid (CF₃CF₂C(O)OH): Three conformations and dimer formation

Perfluoropropionic acid (CF₃CF₂C(O)OH) will be investigated with a focus on its com-plex structural properties. As a formal derivative of propanoic acid, the incorporation of fluorine atoms imparts unique structural features, including three distinct mono-meric conformations and a dimeric structure....

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Della Védova, Carlos Omar, Romano, Rosana Mariel, Stammler, Hans-Georg, Mitzel, Norbert
Formato: Articulo
Lenguaje:Inglés
Publicado: 2025
Materias:
Ciencias Exactas
Perfluoropropionic Acid
Low-Temperature Crystal Structure
Cryogenic Ar-Matrix Study
Conformers
Monomers
Dimer
Computational Calculations
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/178533
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-178533
record_format dspace
spelling I19-R120-10915-1785332025-04-28T20:11:42Z http://sedici.unlp.edu.ar/handle/10915/178533 Perfluoropropionic acid (CF₃CF₂C(O)OH): Three conformations and dimer formation Della Védova, Carlos Omar Romano, Rosana Mariel Stammler, Hans-Georg Mitzel, Norbert 2025-04-23 2025-04-28T15:09:09Z en Ciencias Exactas Perfluoropropionic Acid Low-Temperature Crystal Structure Cryogenic Ar-Matrix Study Conformers Monomers Dimer Computational Calculations Perfluoropropionic acid (CF₃CF₂C(O)OH) will be investigated with a focus on its com-plex structural properties. As a formal derivative of propanoic acid, the incorporation of fluorine atoms imparts unique structural features, including three distinct mono-meric conformations and a dimeric structure. This study presents experimental find-ings, supported by computational modeling, to explore these characteristics. The anal-ysis includes an FTIR study of the isolated species in an Ar-cryogenic matrix and the low-temperature determination of its crystalline structure using single-crystal X-ray diffraction. Facultad de Ciencias Exactas Articulo Articulo http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) application/pdf
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Perfluoropropionic Acid
Low-Temperature Crystal Structure
Cryogenic Ar-Matrix Study
Conformers
Monomers
Dimer
Computational Calculations
spellingShingle Ciencias Exactas
Perfluoropropionic Acid
Low-Temperature Crystal Structure
Cryogenic Ar-Matrix Study
Conformers
Monomers
Dimer
Computational Calculations
Della Védova, Carlos Omar
Romano, Rosana Mariel
Stammler, Hans-Georg
Mitzel, Norbert
Perfluoropropionic acid (CF₃CF₂C(O)OH): Three conformations and dimer formation
topic_facet Ciencias Exactas
Perfluoropropionic Acid
Low-Temperature Crystal Structure
Cryogenic Ar-Matrix Study
Conformers
Monomers
Dimer
Computational Calculations
description Perfluoropropionic acid (CF₃CF₂C(O)OH) will be investigated with a focus on its com-plex structural properties. As a formal derivative of propanoic acid, the incorporation of fluorine atoms imparts unique structural features, including three distinct mono-meric conformations and a dimeric structure. This study presents experimental find-ings, supported by computational modeling, to explore these characteristics. The anal-ysis includes an FTIR study of the isolated species in an Ar-cryogenic matrix and the low-temperature determination of its crystalline structure using single-crystal X-ray diffraction.
format Articulo
Articulo
author Della Védova, Carlos Omar
Romano, Rosana Mariel
Stammler, Hans-Georg
Mitzel, Norbert
author_facet Della Védova, Carlos Omar
Romano, Rosana Mariel
Stammler, Hans-Georg
Mitzel, Norbert
author_sort Della Védova, Carlos Omar
title Perfluoropropionic acid (CF₃CF₂C(O)OH): Three conformations and dimer formation
title_short Perfluoropropionic acid (CF₃CF₂C(O)OH): Three conformations and dimer formation
title_full Perfluoropropionic acid (CF₃CF₂C(O)OH): Three conformations and dimer formation
title_fullStr Perfluoropropionic acid (CF₃CF₂C(O)OH): Three conformations and dimer formation
title_full_unstemmed Perfluoropropionic acid (CF₃CF₂C(O)OH): Three conformations and dimer formation
title_sort perfluoropropionic acid (cf₃cf₂c(o)oh): three conformations and dimer formation
publishDate 2025
url http://sedici.unlp.edu.ar/handle/10915/178533
work_keys_str_mv AT dellavedovacarlosomar perfluoropropionicacidcf3cf2coohthreeconformationsanddimerformation
AT romanorosanamariel perfluoropropionicacidcf3cf2coohthreeconformationsanddimerformation
AT stammlerhansgeorg perfluoropropionicacidcf3cf2coohthreeconformationsanddimerformation
AT mitzelnorbert perfluoropropionicacidcf3cf2coohthreeconformationsanddimerformation
_version_ 1855354209078083584

Ejemplares similares