Structural and spectroscopic behavior of double metal oxalates from the first transition metal series

A series of double metal oxalates of stoichiometry MM’(C2O4)2-4H2O (with MM’ = MnCo, MnNi, MnZn, CoNi, CoCu, CoZn, NiCu, NiZn and CuZn have been prepared and characterized. Their structural behavior was investigated by means of X-ray powder diffractometry, showing a strong structural analogy to the...

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Autores principales:	D'Antonio, María C., Torres, María M., Palacios, Daniel, González Baró, Ana Cecilia, Barone, Vicente Luis, Baran, Enrique José
Formato:	Articulo Comunicacion
Lenguaje:	Inglés
Publicado:	2018
Materias:	Química Double metal oxalates X-ray powder diffractometry structural characteristics IR and Raman spectra vibrational behavior
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/177410
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

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record_format	dspace
spelling	I19-R120-10915-1774102025-03-14T20:12:03Z http://sedici.unlp.edu.ar/handle/10915/177410 Structural and spectroscopic behavior of double metal oxalates from the first transition metal series D'Antonio, María C. Torres, María M. Palacios, Daniel González Baró, Ana Cecilia Barone, Vicente Luis Baran, Enrique José 2018 2025-03-14T17:53:50Z en Química Double metal oxalates X-ray powder diffractometry structural characteristics IR and Raman spectra vibrational behavior A series of double metal oxalates of stoichiometry MM’(C2O4)2-4H2O (with MM’ = MnCo, MnNi, MnZn, CoNi, CoCu, CoZn, NiCu, NiZn and CuZn have been prepared and characterized. Their structural behavior was investigated by means of X-ray powder diffractometry, showing a strong structural analogy to the orthorhombic, so-called β-modification, of the related simple oxalate complexes of composition MC2O4-2H2O. The vibrational spectroscopic behavior of the double metal oxalates was investigated by infrared and Raman spectroscopy. The results clearly confirmed the close structural analogies between the MM’(C2O4)2-4H2O, β-MC2O4-2H2O and α-MC2O4-2H2O series of complexes. Centro de Química Inorgánica Articulo Comunicacion http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) application/pdf 41-41
institution	Universidad Nacional de La Plata
institution_str	I-19
repository_str	R-120
collection	SEDICI (UNLP)
language	Inglés
topic	Química Double metal oxalates X-ray powder diffractometry structural characteristics IR and Raman spectra vibrational behavior
spellingShingle	Química Double metal oxalates X-ray powder diffractometry structural characteristics IR and Raman spectra vibrational behavior D'Antonio, María C. Torres, María M. Palacios, Daniel González Baró, Ana Cecilia Barone, Vicente Luis Baran, Enrique José Structural and spectroscopic behavior of double metal oxalates from the first transition metal series
topic_facet	Química Double metal oxalates X-ray powder diffractometry structural characteristics IR and Raman spectra vibrational behavior
description	A series of double metal oxalates of stoichiometry MM’(C2O4)2-4H2O (with MM’ = MnCo, MnNi, MnZn, CoNi, CoCu, CoZn, NiCu, NiZn and CuZn have been prepared and characterized. Their structural behavior was investigated by means of X-ray powder diffractometry, showing a strong structural analogy to the orthorhombic, so-called β-modification, of the related simple oxalate complexes of composition MC2O4-2H2O. The vibrational spectroscopic behavior of the double metal oxalates was investigated by infrared and Raman spectroscopy. The results clearly confirmed the close structural analogies between the MM’(C2O4)2-4H2O, β-MC2O4-2H2O and α-MC2O4-2H2O series of complexes.
format	Articulo Comunicacion
author	D'Antonio, María C. Torres, María M. Palacios, Daniel González Baró, Ana Cecilia Barone, Vicente Luis Baran, Enrique José
author_facet	D'Antonio, María C. Torres, María M. Palacios, Daniel González Baró, Ana Cecilia Barone, Vicente Luis Baran, Enrique José
author_sort	D'Antonio, María C.
title	Structural and spectroscopic behavior of double metal oxalates from the first transition metal series
title_short	Structural and spectroscopic behavior of double metal oxalates from the first transition metal series
title_full	Structural and spectroscopic behavior of double metal oxalates from the first transition metal series
title_fullStr	Structural and spectroscopic behavior of double metal oxalates from the first transition metal series
title_full_unstemmed	Structural and spectroscopic behavior of double metal oxalates from the first transition metal series
title_sort	structural and spectroscopic behavior of double metal oxalates from the first transition metal series
publishDate	2018
url	http://sedici.unlp.edu.ar/handle/10915/177410
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Structural and spectroscopic behavior of double metal oxalates from the first transition metal series

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