Peculiarities of I-F and I-O bonds in different hypervalent species of iodine

On the basis of calculations of mean amplitudes of vibration a comparative analysis of the properties of I-F and I-O bonds of a wide series of hypervalent iodine compounds is presented. The mean amplitudes of vibration of the I-O bonds are significantly characteristic, whereas those related to the I...

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Autor principal: Baran, Enrique José
Formato: Articulo
Lenguaje:Inglés
Publicado: 2005
Materias:
Química
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/175798
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SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-175798
record_format dspace
spelling I19-R120-10915-1757982025-01-29T20:15:21Z http://sedici.unlp.edu.ar/handle/10915/175798 Peculiarities of I-F and I-O bonds in different hypervalent species of iodine Baran, Enrique José 2005 2025-01-29T14:01:46Z en Química On the basis of calculations of mean amplitudes of vibration a comparative analysis of the properties of I-F and I-O bonds of a wide series of hypervalent iodine compounds is presented. The mean amplitudes of vibration of the I-O bonds are significantly characteristic, whereas those related to the I-F bonds are strongly dependent on the molecular geometry and the oxidation state of iodine, generating important differences between them. The discussion is also extended to some isoelectronic species containing tellurium or xenon. Basado en el cálculo de amplitudes medias de vibración, se presenta un análisis comparativo de las propiedades de los enlaces I-F y I-O en una amplia serie de compuestos hipervalentes de iodo. Las amplitudes medias de vibración para las uniones I-O aparecen claramente características, mientras que las relacionadas a los enlaces I-F dependen fuertemente de la geometría molecular y del estado de oxidación del iodo, generando importantes diferencias entre ellos. La discusión se extiende también a algunas especies isoelectrónicas conteniendo teluro o xenón. Centro de Química Inorgánica Articulo Articulo http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) application/pdf 23-27
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
spellingShingle Química
Baran, Enrique José
Peculiarities of I-F and I-O bonds in different hypervalent species of iodine
topic_facet Química
description On the basis of calculations of mean amplitudes of vibration a comparative analysis of the properties of I-F and I-O bonds of a wide series of hypervalent iodine compounds is presented. The mean amplitudes of vibration of the I-O bonds are significantly characteristic, whereas those related to the I-F bonds are strongly dependent on the molecular geometry and the oxidation state of iodine, generating important differences between them. The discussion is also extended to some isoelectronic species containing tellurium or xenon.
format Articulo
Articulo
author Baran, Enrique José
author_facet Baran, Enrique José
author_sort Baran, Enrique José
title Peculiarities of I-F and I-O bonds in different hypervalent species of iodine
title_short Peculiarities of I-F and I-O bonds in different hypervalent species of iodine
title_full Peculiarities of I-F and I-O bonds in different hypervalent species of iodine
title_fullStr Peculiarities of I-F and I-O bonds in different hypervalent species of iodine
title_full_unstemmed Peculiarities of I-F and I-O bonds in different hypervalent species of iodine
title_sort peculiarities of i-f and i-o bonds in different hypervalent species of iodine
publishDate 2005
url http://sedici.unlp.edu.ar/handle/10915/175798
work_keys_str_mv AT baranenriquejose peculiaritiesofifandiobondsindifferenthypervalentspeciesofiodine
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