Prussian blue analogs: electrosynthesis and characterization

This article focuses on the electrodeposition and in situ characterization of Prussian blue analogs with the generic formula: AMk[Fe(CN)d i-mHf), where h, k, I, m are stoichiometric numbers, A = alkali metal cation, and M is a transitionmetal. Six such metal hexacyanoferrate (MHCF) compounds derived...

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Autores principales: Lezna, Reynaldo Oscar, Tacconi, Norma R. de
Formato: Articulo
Lenguaje:Inglés
Publicado: 2003
Materias:
Química
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/167219
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SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-167219
record_format dspace
spelling I19-R120-10915-1672192024-06-13T20:09:48Z http://sedici.unlp.edu.ar/handle/10915/167219 Prussian blue analogs: electrosynthesis and characterization Lezna, Reynaldo Oscar Tacconi, Norma R. de 2003 2024-06-13T15:15:19Z en Química This article focuses on the electrodeposition and in situ characterization of Prussian blue analogs with the generic formula: AMk[Fe(CN)d i-mHf), where h, k, I, m are stoichiometric numbers, A = alkali metal cation, and M is a transitionmetal. Six such metal hexacyanoferrate (MHCF) compounds derived from Cu, Pd, In, V, Co and Ni are featured in this article. The electrodeposition of MHCF films on targeted substrates is discussed through data obtained by cyclic voltammetry and complementan’ techniques. In situ spectroelectrochemical characterization of these films in the infrared and UV-visible regions is then discussed and constitutes the main topic of this article. Este artículo trata de la caracterización in-situ de películas electrodepositadas de análogos del Azul de Prusia con la fórmula genérica: A.MJ FeíCNjJ¡.mllj), donde h, k, l, m son coeficientes estequiométricos, A es un catión de metal alcalino y M es un metal de transición. La presentación analiza seis hexacianoferrabs metálicos (MHCF) derivados del Cu, Pd, In, V, Co y Ni. La electrodeposición de películas de MHCF sobre sustratos seleccionados, se discute primeramente mediante el análisis de datos obtenidos por voltametría cíclica con la ayuda de técnicas complementaras. La caracterización espectroelectroquímica in-situ de estas películas en las zonas espectrales IR y UV-Visible es luego analizada en detalle y constituye el tópico principal de este trabajo. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Articulo Articulo http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) application/pdf 73-96
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
spellingShingle Química
Lezna, Reynaldo Oscar
Tacconi, Norma R. de
Prussian blue analogs: electrosynthesis and characterization
topic_facet Química
description This article focuses on the electrodeposition and in situ characterization of Prussian blue analogs with the generic formula: AMk[Fe(CN)d i-mHf), where h, k, I, m are stoichiometric numbers, A = alkali metal cation, and M is a transitionmetal. Six such metal hexacyanoferrate (MHCF) compounds derived from Cu, Pd, In, V, Co and Ni are featured in this article. The electrodeposition of MHCF films on targeted substrates is discussed through data obtained by cyclic voltammetry and complementan’ techniques. In situ spectroelectrochemical characterization of these films in the infrared and UV-visible regions is then discussed and constitutes the main topic of this article.
format Articulo
Articulo
author Lezna, Reynaldo Oscar
Tacconi, Norma R. de
author_facet Lezna, Reynaldo Oscar
Tacconi, Norma R. de
author_sort Lezna, Reynaldo Oscar
title Prussian blue analogs: electrosynthesis and characterization
title_short Prussian blue analogs: electrosynthesis and characterization
title_full Prussian blue analogs: electrosynthesis and characterization
title_fullStr Prussian blue analogs: electrosynthesis and characterization
title_full_unstemmed Prussian blue analogs: electrosynthesis and characterization
title_sort prussian blue analogs: electrosynthesis and characterization
publishDate 2003
url http://sedici.unlp.edu.ar/handle/10915/167219
work_keys_str_mv AT leznareynaldooscar prussianblueanalogselectrosynthesisandcharacterization
AT tacconinormarde prussianblueanalogselectrosynthesisandcharacterization
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