Synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex

The complex [Fe(4,4‘-bipy)2(H2O)J(sac)2.2(4,4'-bipy) was obtained in an attempt to prepare a square grid polymer by reaction of tetraaquabis(saccharinato) iron(ll) dihydrate with 4,4'-bipyridine. Its structure was determined by single crystal X-ray diffractometry. It belongs to the monocli...

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Autores principales: Williams, Patricia Ana María, Ferrer, Evelina Gloria, Baran, Enrique José, Piro, Oscar Enrique, Ellena, Javier Alcides, Castellano, Eduardo Ernesto
Formato: Articulo
Lenguaje:Inglés
Publicado: 2002
Materias:
Química
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/164015
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-164015
record_format dspace
spelling I19-R120-10915-1640152024-03-19T20:09:57Z http://sedici.unlp.edu.ar/handle/10915/164015 Synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex Williams, Patricia Ana María Ferrer, Evelina Gloria Baran, Enrique José Piro, Oscar Enrique Ellena, Javier Alcides Castellano, Eduardo Ernesto 2002 2024-03-19T17:35:31Z en Química The complex [Fe(4,4‘-bipy)2(H2O)J(sac)2.2(4,4'-bipy) was obtained in an attempt to prepare a square grid polymer by reaction of tetraaquabis(saccharinato) iron(ll) dihydrate with 4,4'-bipyridine. Its structure was determined by single crystal X-ray diffractometry. It belongs to the monoclinic space group P2,/c with 2 = 2. The Fe(ll) cation is in a slightly distorted octahedral coordination with two 4,4'-bipy and four water molecules as ligands. Its electronic and IR spectra, room temperature magnetic susceptibility and the thermal behavior were also investigated. Durante intentos para la generación de un polímero reticular cuadrado por reacción de tetraacuabis(sacarinato)hierro(ll) dihidrato con 4,4'-bipridina (4,4'-bipy), se obtuvo el complejo simple [Fe(4,4'- bipy)2(H2O)J(sac)2.2(4,4'-bipy). Su estructura fue determinada por difractometría de rayosXen monocristales. Pertenece al sistema cristalino monoclinico P2Jc con 2 = 2. El catión Fe(ll) presenta una coordinación octaédrica ligeramente distorsionada, estando ligado a dos moléculas de 4,4'-bipy y a cuatro moléculas de agua. También se investigaron sus espectros electrónicos y de IR, su susceptibilidad magnética a temperatura ambiente y su comportamiento térmico. Centro de Química Inorgánica Articulo Articulo http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) application/pdf 109-115
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
spellingShingle Química
Williams, Patricia Ana María
Ferrer, Evelina Gloria
Baran, Enrique José
Piro, Oscar Enrique
Ellena, Javier Alcides
Castellano, Eduardo Ernesto
Synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex
topic_facet Química
description The complex [Fe(4,4‘-bipy)2(H2O)J(sac)2.2(4,4'-bipy) was obtained in an attempt to prepare a square grid polymer by reaction of tetraaquabis(saccharinato) iron(ll) dihydrate with 4,4'-bipyridine. Its structure was determined by single crystal X-ray diffractometry. It belongs to the monoclinic space group P2,/c with 2 = 2. The Fe(ll) cation is in a slightly distorted octahedral coordination with two 4,4'-bipy and four water molecules as ligands. Its electronic and IR spectra, room temperature magnetic susceptibility and the thermal behavior were also investigated.
format Articulo
Articulo
author Williams, Patricia Ana María
Ferrer, Evelina Gloria
Baran, Enrique José
Piro, Oscar Enrique
Ellena, Javier Alcides
Castellano, Eduardo Ernesto
author_facet Williams, Patricia Ana María
Ferrer, Evelina Gloria
Baran, Enrique José
Piro, Oscar Enrique
Ellena, Javier Alcides
Castellano, Eduardo Ernesto
author_sort Williams, Patricia Ana María
title Synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex
title_short Synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex
title_full Synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex
title_fullStr Synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex
title_full_unstemmed Synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex
title_sort synthesis and characterization of a new iron (ll)/4,4'-bipyridine complex
publishDate 2002
url http://sedici.unlp.edu.ar/handle/10915/164015
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AT baranenriquejose synthesisandcharacterizationofanewironll44bipyridinecomplex
AT pirooscarenrique synthesisandcharacterizationofanewironll44bipyridinecomplex
AT ellenajavieralcides synthesisandcharacterizationofanewironll44bipyridinecomplex
AT castellanoeduardoernesto synthesisandcharacterizationofanewironll44bipyridinecomplex
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