Microplastics and anthropogenic debris in rainwater from Bahia Blanca, Argentina

Concern about atmospheric microplastic (MP) contamination has increased in recent years. This study assessed the abundance of airborne anthropogenic particles, including MPs, deposited in rainfall in Bahia Blanca, southwest Buenos Aires, Argentina. Rainwater samples were collected monthly from March...

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Autores principales: Villafañe, A. Belén, Ronda, Ana C., Rodríguez Pirani, Lucas Sebastián, Picone, Andrea Lorena, Lucchi, Leandro D., Romano, Rosana Mariel, Pereyra, Marcelo T., Arias, Andrés H.
Formato: Articulo
Lenguaje:Inglés
Publicado: 2023
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/160425
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id I19-R120-10915-160425
record_format dspace
spelling I19-R120-10915-1604252023-11-22T20:07:10Z http://sedici.unlp.edu.ar/handle/10915/160425 Microplastics and anthropogenic debris in rainwater from Bahia Blanca, Argentina Villafañe, A. Belén Ronda, Ana C. Rodríguez Pirani, Lucas Sebastián Picone, Andrea Lorena Lucchi, Leandro D. Romano, Rosana Mariel Pereyra, Marcelo T. Arias, Andrés H. 2023 2023-11-22T17:58:08Z en Química Biología Microplastic atmospheric deposition Plastic fibers μ-Raman South America Concern about atmospheric microplastic (MP) contamination has increased in recent years. This study assessed the abundance of airborne anthropogenic particles, including MPs, deposited in rainfall in Bahia Blanca, southwest Buenos Aires, Argentina. Rainwater samples were collected monthly from March to December 2021 using an active wet-only collector consisting of a glass funnel and a PVC pipe that is only open during rain events. Results obtained show that all rain samples contained anthropogenic debris. The term “anthropogenic debris” is used to refer to the total number of particles as not all the particles found could be determined as plastic. Among all the samples, an average deposition of 77 ± 29 items (anthropogenic debris) m⁻²d⁻¹ was found. The highest deposition was observed in November (148 items m⁻²d⁻¹) while the lowest was found in March (46 items m⁻²d⁻¹). Anthropogenic debris ranged in size from 0.1 mm to 3.87 mm with the most abundant particles being smaller than 1 mm (77.8%). The dominant form of particles found were fibers (95%), followed by fragments (3.1%). Blue color predominated (37.2%) in the total number of samples, followed by light blue (23.3%) and black (21.7%). Further, small particles (<2 mm), apparently composed of mineral material and plastic fibers, were recognized. The chemical composition of suspected MPs was examined by Raman microscopy. The analysis of μ-Raman spectra confirmed the presence of polystyrene, polyethylene terephthalate, and polyethylene vinyl acetate fibers and provided evidence of fibers containing industrial additives such as indigo dye. This is the first assessment of MP pollution in rain in Argentina. Centro de Química Inorgánica Articulo Articulo http://creativecommons.org/licenses/by-nc-nd/4.0/ Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) application/pdf
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Biología
Microplastic atmospheric deposition
Plastic fibers
μ-Raman
South America
spellingShingle Química
Biología
Microplastic atmospheric deposition
Plastic fibers
μ-Raman
South America
Villafañe, A. Belén
Ronda, Ana C.
Rodríguez Pirani, Lucas Sebastián
Picone, Andrea Lorena
Lucchi, Leandro D.
Romano, Rosana Mariel
Pereyra, Marcelo T.
Arias, Andrés H.
Microplastics and anthropogenic debris in rainwater from Bahia Blanca, Argentina
topic_facet Química
Biología
Microplastic atmospheric deposition
Plastic fibers
μ-Raman
South America
description Concern about atmospheric microplastic (MP) contamination has increased in recent years. This study assessed the abundance of airborne anthropogenic particles, including MPs, deposited in rainfall in Bahia Blanca, southwest Buenos Aires, Argentina. Rainwater samples were collected monthly from March to December 2021 using an active wet-only collector consisting of a glass funnel and a PVC pipe that is only open during rain events. Results obtained show that all rain samples contained anthropogenic debris. The term “anthropogenic debris” is used to refer to the total number of particles as not all the particles found could be determined as plastic. Among all the samples, an average deposition of 77 ± 29 items (anthropogenic debris) m⁻²d⁻¹ was found. The highest deposition was observed in November (148 items m⁻²d⁻¹) while the lowest was found in March (46 items m⁻²d⁻¹). Anthropogenic debris ranged in size from 0.1 mm to 3.87 mm with the most abundant particles being smaller than 1 mm (77.8%). The dominant form of particles found were fibers (95%), followed by fragments (3.1%). Blue color predominated (37.2%) in the total number of samples, followed by light blue (23.3%) and black (21.7%). Further, small particles (<2 mm), apparently composed of mineral material and plastic fibers, were recognized. The chemical composition of suspected MPs was examined by Raman microscopy. The analysis of μ-Raman spectra confirmed the presence of polystyrene, polyethylene terephthalate, and polyethylene vinyl acetate fibers and provided evidence of fibers containing industrial additives such as indigo dye. This is the first assessment of MP pollution in rain in Argentina.
format Articulo
Articulo
author Villafañe, A. Belén
Ronda, Ana C.
Rodríguez Pirani, Lucas Sebastián
Picone, Andrea Lorena
Lucchi, Leandro D.
Romano, Rosana Mariel
Pereyra, Marcelo T.
Arias, Andrés H.
author_facet Villafañe, A. Belén
Ronda, Ana C.
Rodríguez Pirani, Lucas Sebastián
Picone, Andrea Lorena
Lucchi, Leandro D.
Romano, Rosana Mariel
Pereyra, Marcelo T.
Arias, Andrés H.
author_sort Villafañe, A. Belén
title Microplastics and anthropogenic debris in rainwater from Bahia Blanca, Argentina
title_short Microplastics and anthropogenic debris in rainwater from Bahia Blanca, Argentina
title_full Microplastics and anthropogenic debris in rainwater from Bahia Blanca, Argentina
title_fullStr Microplastics and anthropogenic debris in rainwater from Bahia Blanca, Argentina
title_full_unstemmed Microplastics and anthropogenic debris in rainwater from Bahia Blanca, Argentina
title_sort microplastics and anthropogenic debris in rainwater from bahia blanca, argentina
publishDate 2023
url http://sedici.unlp.edu.ar/handle/10915/160425
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