Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt)
This dataset includes results on the thermal characterization of waste tires by thermogravimetric analysis. In addition here we report a complete dataset on the analytical pyrolysis (Py-GC/MS) experiments of WT in the presence of different catalysts. The data is complementary to a published paper, t...
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| Formato: | Conjunto de datos |
| Lenguaje: | Inglés |
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2023
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| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/154487 |
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I19-R120-10915-1544872023-06-21T13:37:15Z http://sedici.unlp.edu.ar/handle/10915/154487 Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt) Arteaga Pérez, Luis E. Osorio Vargas, Paula Smith-Azócar, Beatriz Medina, Francisco Campos, Cristian H. 2023-06-21T13:37:15Z 2021 en Ciencias Exactas Química https://purl.org/becyt/ford/1.4 Catalysis Thermogravimetric Analysis Tyre Analytical Pyrolysis This dataset includes results on the thermal characterization of waste tires by thermogravimetric analysis. In addition here we report a complete dataset on the analytical pyrolysis (Py-GC/MS) experiments of WT in the presence of different catalysts. The data is complementary to a published paper, thus a complete description of the materials, methods and equipments used to obtain this dataset is provided in those papers. The experiments were done for waste tires coming from light vehicles, and three metals Pd, Pt, Au deposited on titanate nanotubes (NT-Ti) were used as catalysts for selectively produce valuable chemicals. Experimental factors were the metal nature of the catalyst and the pyrolysis temperature (400 – 450ºC). Moreover, the pyrolysis was investigated for three individual polymers (polyisoprene, butadiene, and styrene-butadiene) to establish possible reaction routes describing the role of metals in the pyrolysis reaction map and product distribution. Three folders are provided here: 1- Raw datafile for TGA of WT recorded in N2 flow between 20 and 650ºC at 10 ºC/min. 2- Datafiles for TurboMass software v5.4 (Perkin Elmer, 2017) with the results of all pyrolytic experiments ordered by materials, temperatures and catalysts nature. 3- Excel files with the retention time, peak area, peak height, among other chromatographic results from the Py-GC/MS. Fil: Arteaga-Pérez, Luis E. Universidad del Bío-Bío. Facultad de Ingeniería. Departamento de Ingeniería en Maderas. Laboratory of Thermal and Catalytic Processes; Chile Fil: Osorio Vargas, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco”. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco”. Comisión de Investigaciones Científicas de la Provincia de Buenos Aires. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco”; Argentina Fil: Smith-Azócar, Beatriz. Universidad del Bío-Bío; Chile Fil: Medina, Francisco. Universidad del Bío-Bío; Chile Fil: Campos, Cristian H. Universidad de Concepción. Facultad de Ciencias Químicas. Departamento de Físico-Química; Chile Facultad de Ciencias Exactas Centro de Investigación y Desarrollo en Ciencias Aplicadas Conjunto de datos Conjunto de datos http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) application/zip The data was measured in a micro-pyrolysis reactor (CDS5200, CDS Analytical Co Ltd.) coupled to a gas chromatograph (Clarus 690, Perkin Emer) equipped with a quadrupole mass detector (SQ8, Perkin Emer). The waste tires were characterized in an elemental analyser (CHNS 628, Leco) and thermogravimetric analysis (Netzsch, model STA 409 PC). Compound identification was done by comparison with the National Institute of Standards and Technology database (NIST, v2016) with the software TurboMass™ v5.4. |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ciencias Exactas Química https://purl.org/becyt/ford/1.4 Catalysis Thermogravimetric Analysis Tyre Analytical Pyrolysis |
| spellingShingle |
Ciencias Exactas Química https://purl.org/becyt/ford/1.4 Catalysis Thermogravimetric Analysis Tyre Analytical Pyrolysis Arteaga Pérez, Luis E. Osorio Vargas, Paula Smith-Azócar, Beatriz Medina, Francisco Campos, Cristian H. Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt) |
| topic_facet |
Ciencias Exactas Química https://purl.org/becyt/ford/1.4 Catalysis Thermogravimetric Analysis Tyre Analytical Pyrolysis |
| description |
This dataset includes results on the thermal characterization of waste tires by thermogravimetric analysis. In addition here we report a complete dataset on the analytical pyrolysis (Py-GC/MS) experiments of WT in the presence of different catalysts. The data is complementary to a published paper, thus a complete description of the materials, methods and equipments used to obtain this dataset is provided in those papers. The experiments were done for waste tires coming from light vehicles, and three metals Pd, Pt, Au deposited on titanate nanotubes (NT-Ti) were used as catalysts for selectively produce valuable chemicals. Experimental factors were the metal nature of the catalyst and the pyrolysis temperature (400 – 450ºC). Moreover, the pyrolysis was investigated for three individual polymers (polyisoprene, butadiene, and styrene-butadiene) to establish possible reaction routes describing the role of metals in the pyrolysis reaction map and product distribution.
Three folders are provided here:
1- Raw datafile for TGA of WT recorded in N2 flow between 20 and 650ºC at 10 ºC/min.
2- Datafiles for TurboMass software v5.4 (Perkin Elmer, 2017) with the results of all pyrolytic experiments ordered by materials, temperatures and catalysts nature.
3- Excel files with the retention time, peak area, peak height, among other chromatographic results from the Py-GC/MS. |
| format |
Conjunto de datos Conjunto de datos |
| author |
Arteaga Pérez, Luis E. Osorio Vargas, Paula Smith-Azócar, Beatriz Medina, Francisco Campos, Cristian H. |
| author_facet |
Arteaga Pérez, Luis E. Osorio Vargas, Paula Smith-Azócar, Beatriz Medina, Francisco Campos, Cristian H. |
| author_sort |
Arteaga Pérez, Luis E. |
| title |
Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt) |
| title_short |
Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt) |
| title_full |
Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt) |
| title_fullStr |
Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt) |
| title_full_unstemmed |
Dataset for waste tire and constituent polymers pyrolysis on Me/NT-Ti (Me = Pd, Au, Pt) |
| title_sort |
dataset for waste tire and constituent polymers pyrolysis on me/nt-ti (me = pd, au, pt) |
| publishDate |
2023 |
| url |
http://sedici.unlp.edu.ar/handle/10915/154487 |
| work_keys_str_mv |
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| _version_ |
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