Square wave pulsating overpotential treatment of chromic acid solution

Systematic investigation of square wave pulsating overpotential (SWPO) treatment of a chromic acid solution is presented. Some preliminary potentio dynamic scans, potentiostatic depos its, potential steps and capacitance vs. potential curves were measured in order to establish the practical range of...

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Autor principal: Egli, Walter Alfredo
Formato: Articulo
Lenguaje:Inglés
Publicado: 2015
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/150293
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id I19-R120-10915-150293
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Chrome electroplating
pulse electrolysis
potentiodynamic scans
potential steps
spellingShingle Química
Chrome electroplating
pulse electrolysis
potentiodynamic scans
potential steps
Egli, Walter Alfredo
Square wave pulsating overpotential treatment of chromic acid solution
topic_facet Química
Chrome electroplating
pulse electrolysis
potentiodynamic scans
potential steps
description Systematic investigation of square wave pulsating overpotential (SWPO) treatment of a chromic acid solution is presented. Some preliminary potentio dynamic scans, potentiostatic depos its, potential steps and capacitance vs. potential curves were measured in order to establish the practical range of the SWPO signal parameters. The results show that properly adjusting the lectrochemical param eters of the cyclic alternating potential perturbation it is possible to obtain cracked or crack free metallic chromium or cromium oxide/hydroxide mixed coatings. The different deposit morpholo gies were characterized through scanning electron microscopy and their chemical composition and micro hardness was measured. Some insight into the possible mechanisms of coating growth under this potential cycling treatment is given.
format Articulo
Articulo
author Egli, Walter Alfredo
author_facet Egli, Walter Alfredo
author_sort Egli, Walter Alfredo
title Square wave pulsating overpotential treatment of chromic acid solution
title_short Square wave pulsating overpotential treatment of chromic acid solution
title_full Square wave pulsating overpotential treatment of chromic acid solution
title_fullStr Square wave pulsating overpotential treatment of chromic acid solution
title_full_unstemmed Square wave pulsating overpotential treatment of chromic acid solution
title_sort square wave pulsating overpotential treatment of chromic acid solution
publishDate 2015
url http://sedici.unlp.edu.ar/handle/10915/150293
work_keys_str_mv AT egliwalteralfredo squarewavepulsatingoverpotentialtreatmentofchromicacidsolution
bdutipo_str Repositorios
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