Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O

The crystal and molecular structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space groupP2₁/n witha=10.072(2),b=19.434(7),c=19.462(3) Å,β=101.07(1)° andZ=4. The anion has a geometry similar to that observed in other related complexes....

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Detalles Bibliográficos
Autores principales: Ronco, Silvia Elisa, Garcia Pose, M. E., Aymonino, Pedro José, Piro, Oscar Enrique, Rivero, Blas Eduardo, Mercader, Roberto Carlos, Castellano, Eduardo Ernesto
Formato: Articulo
Lenguaje:Inglés
Publicado: 1986
Materias:
Física
Química
Hydrogen
Nitrogen
Iron
2H2O
Water Molecule
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/146535
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-146535
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Física
Química
Hydrogen
Nitrogen
Iron
2H2O
Water Molecule
spellingShingle Física
Química
Hydrogen
Nitrogen
Iron
2H2O
Water Molecule
Ronco, Silvia Elisa
Garcia Pose, M. E.
Aymonino, Pedro José
Piro, Oscar Enrique
Rivero, Blas Eduardo
Mercader, Roberto Carlos
Castellano, Eduardo Ernesto
Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
topic_facet Física
Química
Hydrogen
Nitrogen
Iron
2H2O
Water Molecule
description The crystal and molecular structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space groupP2₁/n witha=10.072(2),b=19.434(7),c=19.462(3) Å,β=101.07(1)° andZ=4. The anion has a geometry similar to that observed in other related complexes. The two water molecules are hydrogen bonded to each other and are located at van der Waals distances from nitrogen atoms of neighbor nitroprusside anions.
format Articulo
Articulo
author Ronco, Silvia Elisa
Garcia Pose, M. E.
Aymonino, Pedro José
Piro, Oscar Enrique
Rivero, Blas Eduardo
Mercader, Roberto Carlos
Castellano, Eduardo Ernesto
author_facet Ronco, Silvia Elisa
Garcia Pose, M. E.
Aymonino, Pedro José
Piro, Oscar Enrique
Rivero, Blas Eduardo
Mercader, Roberto Carlos
Castellano, Eduardo Ernesto
author_sort Ronco, Silvia Elisa
title Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_short Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_full Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_fullStr Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_full_unstemmed Crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(II) nitroprusside dihydrate: [Fe(o-phen)₃]-[Fe(CN)₅NO]·2H₂O
title_sort crystal and molecular structure and spectroscopic properties of tris(o-phenanthroline)iron(ii) nitroprusside dihydrate: [fe(o-phen)₃]-[fe(cn)₅no]·2h₂o
publishDate 1986
url http://sedici.unlp.edu.ar/handle/10915/146535
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