Alkali-peroxide treatment of sugar cane bagasse : Effect of chemical charges on the efficiency of xylan isolation and susceptibility of bagasse to saccharification

Sugar cane is a promising raw material for the extraction of hemicelluloses. An alkali treatment of sugar cane bagasse under proper conditions followed by a precipitation using a reasonable quantity of ethanol can be an effective method to isolate these polysaccharides. In this work, bagasse is trea...

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Autores principales: Solier, Yamil Nahún, Mocchiutti, Paulina, Cabrera, María Noel, Saparrat, Mario Carlos Nazareno, Zanuttini, Miguel Ángel Mario, Inalbon, María Cristina
Formato: Articulo Preprint
Lenguaje:Inglés
Publicado: 2022
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/146478
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id I19-R120-10915-146478
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ingeniería
Química
Hemicellulose extraction
Alkali consumption
Peroxide effect
Enzymatic hydrolysis
spellingShingle Ingeniería
Química
Hemicellulose extraction
Alkali consumption
Peroxide effect
Enzymatic hydrolysis
Solier, Yamil Nahún
Mocchiutti, Paulina
Cabrera, María Noel
Saparrat, Mario Carlos Nazareno
Zanuttini, Miguel Ángel Mario
Inalbon, María Cristina
Alkali-peroxide treatment of sugar cane bagasse : Effect of chemical charges on the efficiency of xylan isolation and susceptibility of bagasse to saccharification
topic_facet Ingeniería
Química
Hemicellulose extraction
Alkali consumption
Peroxide effect
Enzymatic hydrolysis
description Sugar cane is a promising raw material for the extraction of hemicelluloses. An alkali treatment of sugar cane bagasse under proper conditions followed by a precipitation using a reasonable quantity of ethanol can be an effective method to isolate these polysaccharides. In this work, bagasse is treated to obtain two products: (a) polymeric hemicellulose and (b) an enzymatic hydrolysate from the treated bagasse after hemicellulose extraction. The effects of charges of sodium hydroxide (10, 20, 40% w/w) and hydrogen peroxide (0, 10, 20% w/w) in the alkali treatment were evaluated. A 3² experimental design was considered under control of metal ions and inert atmosphere during alkaline treatment. An acceptable proportion of xylose plus arabinose could be extracted from bagasse (up to 18.4 g/100 g of bagasse). Both the alkali and peroxide showed strong effects on the yield of the extraction, as well as on the yield of the precipitation in ethanol-water solution. Besides, the susceptibility of bagasse for cellulolytic enzymatic hydrolysis is improved. The highest hemicellulose precipitation yield was 85% which corresponded to the treatment with the highest alkali charge without peroxide. The highest yield of enzymatic hydrolysis was obtained for the highest alkali and peroxide charges.
format Articulo
Preprint
author Solier, Yamil Nahún
Mocchiutti, Paulina
Cabrera, María Noel
Saparrat, Mario Carlos Nazareno
Zanuttini, Miguel Ángel Mario
Inalbon, María Cristina
author_facet Solier, Yamil Nahún
Mocchiutti, Paulina
Cabrera, María Noel
Saparrat, Mario Carlos Nazareno
Zanuttini, Miguel Ángel Mario
Inalbon, María Cristina
author_sort Solier, Yamil Nahún
title Alkali-peroxide treatment of sugar cane bagasse : Effect of chemical charges on the efficiency of xylan isolation and susceptibility of bagasse to saccharification
title_short Alkali-peroxide treatment of sugar cane bagasse : Effect of chemical charges on the efficiency of xylan isolation and susceptibility of bagasse to saccharification
title_full Alkali-peroxide treatment of sugar cane bagasse : Effect of chemical charges on the efficiency of xylan isolation and susceptibility of bagasse to saccharification
title_fullStr Alkali-peroxide treatment of sugar cane bagasse : Effect of chemical charges on the efficiency of xylan isolation and susceptibility of bagasse to saccharification
title_full_unstemmed Alkali-peroxide treatment of sugar cane bagasse : Effect of chemical charges on the efficiency of xylan isolation and susceptibility of bagasse to saccharification
title_sort alkali-peroxide treatment of sugar cane bagasse : effect of chemical charges on the efficiency of xylan isolation and susceptibility of bagasse to saccharification
publishDate 2022
url http://sedici.unlp.edu.ar/handle/10915/146478
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