Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O

The crystal structure of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O, has been determined from X-ray diffraction data and refined using direct and Fourier methods to R = 0.066 and Rw = 0.075, employing 1894 independent reflections with I > 3 (I). The substance crystallizes in the mon...

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Detalles Bibliográficos
Autores principales: Soria, Delia Beatriz, Piro, Oscar Enrique, Castellano, Eduardo Ernesto, Aymonino, Pedro José
Formato: Articulo
Lenguaje:Inglés
Publicado: 1999
Materias:
Química
Rubidium nitroprusside monohydrate
Crystal structure
Properties
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/146429
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-146429
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Rubidium nitroprusside monohydrate
Crystal structure
Properties
spellingShingle Química
Rubidium nitroprusside monohydrate
Crystal structure
Properties
Soria, Delia Beatriz
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O
topic_facet Química
Rubidium nitroprusside monohydrate
Crystal structure
Properties
description The crystal structure of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O, has been determined from X-ray diffraction data and refined using direct and Fourier methods to R = 0.066 and Rw = 0.075, employing 1894 independent reflections with I > 3 (I). The substance crystallizes in the monoclinic space group C2/c (C62h), with a = 13.987(2), b = 10.241(1), c = 18.151(1) Å, β = 110.94°, and Z = 8. Anions are located at C1 sites, one per asymmetric unit, and are slightly distorted octahedra. TGA, DTA, FTIR, and FTIR Raman results were interpreted on the basis of the formula of the compound, its crystal structure, and the behavior of other nitroprussides.
format Articulo
Articulo
author Soria, Delia Beatriz
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
author_facet Soria, Delia Beatriz
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
author_sort Soria, Delia Beatriz
title Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O
title_short Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O
title_full Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O
title_fullStr Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O
title_full_unstemmed Crystal and molecular structure determination, TGA, DTA, and infrared and Raman spectra of rubidium nitroprusside monohydrate, Rb₂[Fe(CN)₅NO] . H₂O
title_sort crystal and molecular structure determination, tga, dta, and infrared and raman spectra of rubidium nitroprusside monohydrate, rb₂[fe(cn)₅no] . h₂o
publishDate 1999
url http://sedici.unlp.edu.ar/handle/10915/146429
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bdutipo_str Repositorios
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