Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat

The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its dep...

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Detalles Bibliográficos
Autores principales: Ferrer, Evelina Gloria, Etcheverry, Susana Beatriz, Baran, Enrique José
Formato: Articulo
Lenguaje:Alemán
Publicado: 1993
Materias:
Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/146414
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-146414
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Alemán
topic Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
spellingShingle Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
Ferrer, Evelina Gloria
Etcheverry, Susana Beatriz
Baran, Enrique José
Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
topic_facet Química
Vanadyl(IV) saccharinate
IR spectra
Electronic spectra
Magnetic and thermal behaviour
description The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.
format Articulo
Articulo
author Ferrer, Evelina Gloria
Etcheverry, Susana Beatriz
Baran, Enrique José
author_facet Ferrer, Evelina Gloria
Etcheverry, Susana Beatriz
Baran, Enrique José
author_sort Ferrer, Evelina Gloria
title Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_short Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_full Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_fullStr Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_full_unstemmed Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat
title_sort darstellung und eigenschaften von vanadyl(iv)-saccharinat
publishDate 1993
url http://sedici.unlp.edu.ar/handle/10915/146414
work_keys_str_mv AT ferrerevelinagloria darstellungundeigenschaftenvonvanadylivsaccharinat
AT etcheverrysusanabeatriz darstellungundeigenschaftenvonvanadylivsaccharinat
AT baranenriquejose darstellungundeigenschaftenvonvanadylivsaccharinat
bdutipo_str Repositorios
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