Spectroscopic and magnetic properties of a Ni(II) complex with citric acid

The complex compound K₂[Ni(cit)(H₂O)₂]₂·4H₂O (cit = triionized citrate ion) seems to be a good model for the investigation of Ni(II)/citrate interactions that are of interest in relation to nickel metabolism and bioaccumulation. Its infrared and Raman spectra were recorded and analyzed on the basis...

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Autores principales: Bovi Mitre, M. G., Wierna, Norma Rosario, Wagner, Claudia Cecilia, Baran, Enrique José
Formato: Articulo
Lenguaje:Inglés
Publicado: 2000
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/146411
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id I19-R120-10915-146411
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Nickel
Citrate
Raman spectrum
IR spectrum
Magnetic susceptibility
spellingShingle Química
Nickel
Citrate
Raman spectrum
IR spectrum
Magnetic susceptibility
Bovi Mitre, M. G.
Wierna, Norma Rosario
Wagner, Claudia Cecilia
Baran, Enrique José
Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
topic_facet Química
Nickel
Citrate
Raman spectrum
IR spectrum
Magnetic susceptibility
description The complex compound K₂[Ni(cit)(H₂O)₂]₂·4H₂O (cit = triionized citrate ion) seems to be a good model for the investigation of Ni(II)/citrate interactions that are of interest in relation to nickel metabolism and bioaccumulation. Its infrared and Raman spectra were recorded and analyzed on the basis of its structural peculiarities. The magnetic susceptibility, investigated in the temperature range between 1.9 and 300 K, shows the absence of magnetic interactions between the two metal centers present in this structure.
format Articulo
Articulo
author Bovi Mitre, M. G.
Wierna, Norma Rosario
Wagner, Claudia Cecilia
Baran, Enrique José
author_facet Bovi Mitre, M. G.
Wierna, Norma Rosario
Wagner, Claudia Cecilia
Baran, Enrique José
author_sort Bovi Mitre, M. G.
title Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_short Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_full Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_fullStr Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_full_unstemmed Spectroscopic and magnetic properties of a Ni(II) complex with citric acid
title_sort spectroscopic and magnetic properties of a ni(ii) complex with citric acid
publishDate 2000
url http://sedici.unlp.edu.ar/handle/10915/146411
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