Biotransformation of biphenyl by the filamentous fungus <i>Talaromyces helicus</i>
The filamentous fungus <i>Talaromyces helicus</i>, isolated from oil-contaminated sludge, oxidizes biphenyl via 4-hydroxybiphenyl to the dihydroxylated derivatives 4,4′-dihydroxybiphenyl and 3,4-dihydroxybiphenyl, which, to a certain extent, are converted to glycosyl conjugates. The suga...
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Autores principales: | , , , , |
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Formato: | Articulo |
Lenguaje: | Inglés |
Publicado: |
2005
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Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/146254 |
Aporte de: |
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I19-R120-10915-146254 |
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institution |
Universidad Nacional de La Plata |
institution_str |
I-19 |
repository_str |
R-120 |
collection |
SEDICI (UNLP) |
language |
Inglés |
topic |
Ciencias Naturales Ciencias Exactas biphenyl degradation filamentous fungi oxidation products ring fission Talaromyces |
spellingShingle |
Ciencias Naturales Ciencias Exactas biphenyl degradation filamentous fungi oxidation products ring fission Talaromyces Romero, María Cristina Hammer, Elke Hanschke, Renate Arambarri, Angélica Margarita Schauer, Frieder Biotransformation of biphenyl by the filamentous fungus <i>Talaromyces helicus</i> |
topic_facet |
Ciencias Naturales Ciencias Exactas biphenyl degradation filamentous fungi oxidation products ring fission Talaromyces |
description |
The filamentous fungus <i>Talaromyces helicus</i>, isolated from oil-contaminated sludge, oxidizes biphenyl via 4-hydroxybiphenyl to the dihydroxylated derivatives 4,4′-dihydroxybiphenyl and 3,4-dihydroxybiphenyl, which, to a certain extent, are converted to glycosyl conjugates. The sugar moiety of the conjugate formed from 4,4′-dihydroxybiphenyl was identified as glucose. Further metabolites: 2-hydroxybiphenyl, 2,5-dihydroxylated biphenyl, and the ring cleavage product 4-phenyl-2-pyrone-6-carboxylic acid accumulated only in traces. From these results the main pathway for biotransformation of biphenyl in <i>T. helicus</i> could be proposed to be the excretion of dihydroxylated derivatives (>75%) and their glucosyl conjugates (<25%). |
format |
Articulo Articulo |
author |
Romero, María Cristina Hammer, Elke Hanschke, Renate Arambarri, Angélica Margarita Schauer, Frieder |
author_facet |
Romero, María Cristina Hammer, Elke Hanschke, Renate Arambarri, Angélica Margarita Schauer, Frieder |
author_sort |
Romero, María Cristina |
title |
Biotransformation of biphenyl by the filamentous fungus <i>Talaromyces helicus</i> |
title_short |
Biotransformation of biphenyl by the filamentous fungus <i>Talaromyces helicus</i> |
title_full |
Biotransformation of biphenyl by the filamentous fungus <i>Talaromyces helicus</i> |
title_fullStr |
Biotransformation of biphenyl by the filamentous fungus <i>Talaromyces helicus</i> |
title_full_unstemmed |
Biotransformation of biphenyl by the filamentous fungus <i>Talaromyces helicus</i> |
title_sort |
biotransformation of biphenyl by the filamentous fungus <i>talaromyces helicus</i> |
publishDate |
2005 |
url |
http://sedici.unlp.edu.ar/handle/10915/146254 |
work_keys_str_mv |
AT romeromariacristina biotransformationofbiphenylbythefilamentousfungusitalaromyceshelicusi AT hammerelke biotransformationofbiphenylbythefilamentousfungusitalaromyceshelicusi AT hanschkerenate biotransformationofbiphenylbythefilamentousfungusitalaromyceshelicusi AT arambarriangelicamargarita biotransformationofbiphenylbythefilamentousfungusitalaromyceshelicusi AT schauerfrieder biotransformationofbiphenylbythefilamentousfungusitalaromyceshelicusi |
bdutipo_str |
Repositorios |
_version_ |
1764820460905693186 |