Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]

The title compound, Rb2[Fe(CN)5NO], crystallizes in the space group P212121, witha=5.687(1),b=15.956(2),c=12.645(3) A, andZ=4. Anions are in equivalent C1 sites (one per asymmetric unit) and are slightly distorted octahedra (C4v ideal symmetry). TGA and DTA curves and vibrational (infrared and Raman...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Soria, Delia Beatriz, Amalvy, Javier Ignacio, Piro, Oscar Enrique, Castellano, Eduardo Ernesto, Aymonino, Pedro José
Formato: Articulo
Lenguaje:Inglés
Publicado: 1996
Materias:
Química
Crystal structure
rubidium nitroprusside
IR
Raman
thermal analysis
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/145001
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:The title compound, Rb2[Fe(CN)5NO], crystallizes in the space group P212121, witha=5.687(1),b=15.956(2),c=12.645(3) A, andZ=4. Anions are in equivalent C1 sites (one per asymmetric unit) and are slightly distorted octahedra (C4v ideal symmetry). TGA and DTA curves and vibrational (infrared and Raman) spectra of Rb2[Fe(CN)5NO] were obtained. Results are interpreted in view of the crystal structure of the compound and the behavior of related substances.

Ejemplares similares