Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]

The title compound, Rb2[Fe(CN)5NO], crystallizes in the space group P212121, witha=5.687(1),b=15.956(2),c=12.645(3) A, andZ=4. Anions are in equivalent C1 sites (one per asymmetric unit) and are slightly distorted octahedra (C4v ideal symmetry). TGA and DTA curves and vibrational (infrared and Raman...

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Detalles Bibliográficos
Autores principales: Soria, Delia Beatriz, Amalvy, Javier Ignacio, Piro, Oscar Enrique, Castellano, Eduardo Ernesto, Aymonino, Pedro José
Formato: Articulo
Lenguaje:Inglés
Publicado: 1996
Materias:
IR
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/145001
Aporte de:
id I19-R120-10915-145001
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Crystal structure
rubidium nitroprusside
IR
Raman
thermal analysis
spellingShingle Química
Crystal structure
rubidium nitroprusside
IR
Raman
thermal analysis
Soria, Delia Beatriz
Amalvy, Javier Ignacio
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]
topic_facet Química
Crystal structure
rubidium nitroprusside
IR
Raman
thermal analysis
description The title compound, Rb2[Fe(CN)5NO], crystallizes in the space group P212121, witha=5.687(1),b=15.956(2),c=12.645(3) A, andZ=4. Anions are in equivalent C1 sites (one per asymmetric unit) and are slightly distorted octahedra (C4v ideal symmetry). TGA and DTA curves and vibrational (infrared and Raman) spectra of Rb2[Fe(CN)5NO] were obtained. Results are interpreted in view of the crystal structure of the compound and the behavior of related substances.
format Articulo
Articulo
author Soria, Delia Beatriz
Amalvy, Javier Ignacio
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
author_facet Soria, Delia Beatriz
Amalvy, Javier Ignacio
Piro, Oscar Enrique
Castellano, Eduardo Ernesto
Aymonino, Pedro José
author_sort Soria, Delia Beatriz
title Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]
title_short Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]
title_full Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]
title_fullStr Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]
title_full_unstemmed Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb<SUB>2</SUB>[Fe(CN)<SUB>5</SUB>NO]
title_sort crystal and molecular structure determination, tga-dta, and infrared and raman spectra of rubidium nitroprusside, rb<sub>2</sub>[fe(cn)<sub>5</sub>no]
publishDate 1996
url http://sedici.unlp.edu.ar/handle/10915/145001
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