Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)

The thermal behaviour of the MH₂(IO₃)₃ (M=K, Rb and NH₄) isomorphous compounds, as well as the IR and Raman spectra have been investigated as part of a study of the properties of solid protonic conductors. Detailed stoichiometries, sustained by TG, DTA, XRD and IR analysis, have been developed into...

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Detalles Bibliográficos
Autores principales: Vassallo, Marta Beatriz, Botto, Irma Lía
Formato: Articulo
Lenguaje:Inglés
Publicado: 1992
Materias:
Química
Isomorphous compounds
Solid protonic conductors
TG
DTA
XRD
IR
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/142626
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-142626
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Isomorphous compounds
Solid protonic conductors
TG
DTA
XRD
IR
spellingShingle Química
Isomorphous compounds
Solid protonic conductors
TG
DTA
XRD
IR
Vassallo, Marta Beatriz
Botto, Irma Lía
Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)
topic_facet Química
Isomorphous compounds
Solid protonic conductors
TG
DTA
XRD
IR
description The thermal behaviour of the MH₂(IO₃)₃ (M=K, Rb and NH₄) isomorphous compounds, as well as the IR and Raman spectra have been investigated as part of a study of the properties of solid protonic conductors. Detailed stoichiometries, sustained by TG, DTA, XRD and IR analysis, have been developed into the three phases. There were also evidences of the formation of the [I₃O₈]− polymeric phases. Their stabilities were associated to the different polarizing power of the H, K and Rb cations.
format Articulo
Articulo
author Vassallo, Marta Beatriz
Botto, Irma Lía
author_facet Vassallo, Marta Beatriz
Botto, Irma Lía
author_sort Vassallo, Marta Beatriz
title Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)
title_short Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)
title_full Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)
title_fullStr Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)
title_full_unstemmed Thermal behaviour and vibrational characterization of MH₂(IO₃)₃ phases (M=K, Rb and NH₄)
title_sort thermal behaviour and vibrational characterization of mh₂(io₃)₃ phases (m=k, rb and nh₄)
publishDate 1992
url http://sedici.unlp.edu.ar/handle/10915/142626
work_keys_str_mv AT vassallomartabeatriz thermalbehaviourandvibrationalcharacterizationofmh2io33phasesmkrbandnh4
AT bottoirmalia thermalbehaviourandvibrationalcharacterizationofmh2io33phasesmkrbandnh4
bdutipo_str Repositorios
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