Molecular structure and semiexternal molecular motions in 2,4,5-trichlorobenzenesulfonyl chloride, C6H2Cl4O2S
The molecular structure of 2,4,5-trichlorobenzenesulfonyl chloride has been determined by X-ray diffraction methods. The compound is orthorhombic,Aba2, witha=16.253(12),b=17.016(9),c=7.146(5) A,V=1976(5) A3,Z=8,D=1.88 kg·mm−3, (MoKα)=0.7107 A,μ=136.8 cm−1,F(000)=1104. Data were obtained at room temp...
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| Autores principales: | , , , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1988
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| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/140379 |
| Aporte de: |
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I19-R120-10915-140379 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Física Ciencias Exactas Crystallography molecular structure 2, 4, 5-trichlorobenzenesulfonyl chloride |
| spellingShingle |
Física Ciencias Exactas Crystallography molecular structure 2, 4, 5-trichlorobenzenesulfonyl chloride Rigotti, Guillermo Alzari, Pedro M. Navaza, A. Wolfenson, A. E. Pusiol, D. J. Brunetti, A. H. Molecular structure and semiexternal molecular motions in 2,4,5-trichlorobenzenesulfonyl chloride, C6H2Cl4O2S |
| topic_facet |
Física Ciencias Exactas Crystallography molecular structure 2, 4, 5-trichlorobenzenesulfonyl chloride |
| description |
The molecular structure of 2,4,5-trichlorobenzenesulfonyl chloride has been determined by X-ray diffraction methods. The compound is orthorhombic,Aba2, witha=16.253(12),b=17.016(9),c=7.146(5) A,V=1976(5) A3,Z=8,D=1.88 kg·mm−3, (MoKα)=0.7107 A,μ=136.8 cm−1,F(000)=1104. Data were obtained at room temperature; the finalR is 0.029 for 854 independent reflections. The substituted benzene ring is planar within experimental accuracy, the dihedral angle with the C(1)-S(1)-Cl(1) plane being 66.0(5)°. The compound has normal bond lengths and angles; some short intramolecular distances account for the maintenance of the rigid benzene frame. No significatively short intermolecular distances have been found. Confirmation of the oscillatory character of the semiexternal molecular motions operating above 180 K is accounted for. |
| format |
Articulo Articulo |
| author |
Rigotti, Guillermo Alzari, Pedro M. Navaza, A. Wolfenson, A. E. Pusiol, D. J. Brunetti, A. H. |
| author_facet |
Rigotti, Guillermo Alzari, Pedro M. Navaza, A. Wolfenson, A. E. Pusiol, D. J. Brunetti, A. H. |
| author_sort |
Rigotti, Guillermo |
| title |
Molecular structure and semiexternal molecular motions in 2,4,5-trichlorobenzenesulfonyl chloride, C6H2Cl4O2S |
| title_short |
Molecular structure and semiexternal molecular motions in 2,4,5-trichlorobenzenesulfonyl chloride, C6H2Cl4O2S |
| title_full |
Molecular structure and semiexternal molecular motions in 2,4,5-trichlorobenzenesulfonyl chloride, C6H2Cl4O2S |
| title_fullStr |
Molecular structure and semiexternal molecular motions in 2,4,5-trichlorobenzenesulfonyl chloride, C6H2Cl4O2S |
| title_full_unstemmed |
Molecular structure and semiexternal molecular motions in 2,4,5-trichlorobenzenesulfonyl chloride, C6H2Cl4O2S |
| title_sort |
molecular structure and semiexternal molecular motions in 2,4,5-trichlorobenzenesulfonyl chloride, c6h2cl4o2s |
| publishDate |
1988 |
| url |
http://sedici.unlp.edu.ar/handle/10915/140379 |
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AT rigottiguillermo molecularstructureandsemiexternalmolecularmotionsin245trichlorobenzenesulfonylchloridec6h2cl4o2s AT alzaripedrom molecularstructureandsemiexternalmolecularmotionsin245trichlorobenzenesulfonylchloridec6h2cl4o2s AT navazaa molecularstructureandsemiexternalmolecularmotionsin245trichlorobenzenesulfonylchloridec6h2cl4o2s AT wolfensonae molecularstructureandsemiexternalmolecularmotionsin245trichlorobenzenesulfonylchloridec6h2cl4o2s AT pusioldj molecularstructureandsemiexternalmolecularmotionsin245trichlorobenzenesulfonylchloridec6h2cl4o2s AT brunettiah molecularstructureandsemiexternalmolecularmotionsin245trichlorobenzenesulfonylchloridec6h2cl4o2s |
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Repositorios |
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1764820458701586433 |