The electrochemical facetting of metal surfaces : Preferred crystallographic orientation and roughening effects in electrocatalysis

New electrochemical procedures to develop highly rough and preferentially oriented surfaces at face-centered cubic metals are described. The structure and morphology of the different surfaces have been studied through scanning electron and scanning tunneling microscopy. The mechanisms of the process...

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Autores principales: Triaca, Walter Enrique, Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1990
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/139025
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id I19-R120-10915-139025
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Física
electrochemical procedures
face-centered cubic metals
microscopy
spellingShingle Ciencias Exactas
Física
electrochemical procedures
face-centered cubic metals
microscopy
Triaca, Walter Enrique
Arvia, Alejandro Jorge
The electrochemical facetting of metal surfaces : Preferred crystallographic orientation and roughening effects in electrocatalysis
topic_facet Ciencias Exactas
Física
electrochemical procedures
face-centered cubic metals
microscopy
description New electrochemical procedures to develop highly rough and preferentially oriented surfaces at face-centered cubic metals are described. The structure and morphology of the different surfaces have been studied through scanning electron and scanning tunneling microscopy. The mechanisms of the processes involved in the development of roughening and preferred crystallographic orientation are discussed on the basis of electrochemical data for platinum in acid electrolytes. The electrochemical behaviour of the new electrode surfaces has been tested for different reactions, such as the electro-oxidation of adsorbed carbon monoxide on preferentially oriented platinum and the adsorption and electrooxidation of both ethylene and reduced carbon dioxide on electrodispersed platinum.
format Articulo
Articulo
author Triaca, Walter Enrique
Arvia, Alejandro Jorge
author_facet Triaca, Walter Enrique
Arvia, Alejandro Jorge
author_sort Triaca, Walter Enrique
title The electrochemical facetting of metal surfaces : Preferred crystallographic orientation and roughening effects in electrocatalysis
title_short The electrochemical facetting of metal surfaces : Preferred crystallographic orientation and roughening effects in electrocatalysis
title_full The electrochemical facetting of metal surfaces : Preferred crystallographic orientation and roughening effects in electrocatalysis
title_fullStr The electrochemical facetting of metal surfaces : Preferred crystallographic orientation and roughening effects in electrocatalysis
title_full_unstemmed The electrochemical facetting of metal surfaces : Preferred crystallographic orientation and roughening effects in electrocatalysis
title_sort electrochemical facetting of metal surfaces : preferred crystallographic orientation and roughening effects in electrocatalysis
publishDate 1990
url http://sedici.unlp.edu.ar/handle/10915/139025
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