Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)

The crystal structure of the title complex, [Cd(tsac)2(H2O)], has been determined by single crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/c (a = 12.236(3), b = 8.919(3), c = 16.655(3) A, β = 96.18(2)°, Z = 4). The molecular structure was solved from 1705 indepen...

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Detalles Bibliográficos
Autores principales: Tarulli, Susana H., Quinzani, Oscar V., Piro, Oscar Enrique, Baran, Enrique José, Castellano, Eduardo E.
Formato: Articulo
Lenguaje:Inglés
Publicado: 2001
Materias:
Ciencias Exactas
Química
Cadmium(II)
Thiosaccharinate complex
Structure elucidation
IR spectroscopy
Raman spectroscopy
Thermochemistry
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/138186
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:The crystal structure of the title complex, [Cd(tsac)2(H2O)], has been determined by single crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/c (a = 12.236(3), b = 8.919(3), c = 16.655(3) A, β = 96.18(2)°, Z = 4). The molecular structure was solved from 1705 independent reflections with I > σ(I) and refined to R1 = 0.0489. Infrared and Raman spectra of the complex were recorded and are briefly discussed. Its thermal behaviour was investigated by thermogravimetry and differential thermal analysis.

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