Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)

The crystal structure of the title complex, [Cd(tsac)2(H2O)], has been determined by single crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/c (a = 12.236(3), b = 8.919(3), c = 16.655(3) A, β = 96.18(2)°, Z = 4). The molecular structure was solved from 1705 indepen...

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Autores principales: Tarulli, Susana H., Quinzani, Oscar V., Piro, Oscar Enrique, Baran, Enrique José, Castellano, Eduardo E.
Formato: Articulo
Lenguaje:Inglés
Publicado: 2001
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/138186
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id I19-R120-10915-138186
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Ciencias Exactas
Química
Cadmium(II)
Thiosaccharinate complex
Structure elucidation
IR spectroscopy
Raman spectroscopy
Thermochemistry
spellingShingle Ciencias Exactas
Química
Cadmium(II)
Thiosaccharinate complex
Structure elucidation
IR spectroscopy
Raman spectroscopy
Thermochemistry
Tarulli, Susana H.
Quinzani, Oscar V.
Piro, Oscar Enrique
Baran, Enrique José
Castellano, Eduardo E.
Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)
topic_facet Ciencias Exactas
Química
Cadmium(II)
Thiosaccharinate complex
Structure elucidation
IR spectroscopy
Raman spectroscopy
Thermochemistry
description The crystal structure of the title complex, [Cd(tsac)2(H2O)], has been determined by single crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/c (a = 12.236(3), b = 8.919(3), c = 16.655(3) A, β = 96.18(2)°, Z = 4). The molecular structure was solved from 1705 independent reflections with I > σ(I) and refined to R1 = 0.0489. Infrared and Raman spectra of the complex were recorded and are briefly discussed. Its thermal behaviour was investigated by thermogravimetry and differential thermal analysis.
format Articulo
Articulo
author Tarulli, Susana H.
Quinzani, Oscar V.
Piro, Oscar Enrique
Baran, Enrique José
Castellano, Eduardo E.
author_facet Tarulli, Susana H.
Quinzani, Oscar V.
Piro, Oscar Enrique
Baran, Enrique José
Castellano, Eduardo E.
author_sort Tarulli, Susana H.
title Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)
title_short Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)
title_full Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)
title_fullStr Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)
title_full_unstemmed Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)
title_sort structural, spectroscopic, and thermal behaviour of bis-(thiosaccharinate)- aqua-cadmium(ii)
publishDate 2001
url http://sedici.unlp.edu.ar/handle/10915/138186
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