Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II)
The crystal structure of the title complex, [Cd(tsac)2(H2O)], has been determined by single crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/c (a = 12.236(3), b = 8.919(3), c = 16.655(3) A, β = 96.18(2)°, Z = 4). The molecular structure was solved from 1705 indepen...
Guardado en:
| Autores principales: | , , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2001
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/138186 |
| Aporte de: |
| id |
I19-R120-10915-138186 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ciencias Exactas Química Cadmium(II) Thiosaccharinate complex Structure elucidation IR spectroscopy Raman spectroscopy Thermochemistry |
| spellingShingle |
Ciencias Exactas Química Cadmium(II) Thiosaccharinate complex Structure elucidation IR spectroscopy Raman spectroscopy Thermochemistry Tarulli, Susana H. Quinzani, Oscar V. Piro, Oscar Enrique Baran, Enrique José Castellano, Eduardo E. Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II) |
| topic_facet |
Ciencias Exactas Química Cadmium(II) Thiosaccharinate complex Structure elucidation IR spectroscopy Raman spectroscopy Thermochemistry |
| description |
The crystal structure of the title complex, [Cd(tsac)2(H2O)], has been determined by single crystal X-ray diffraction methods. It crystallizes in the monoclinic space group C2/c (a = 12.236(3), b = 8.919(3), c = 16.655(3) A, β = 96.18(2)°, Z = 4). The molecular structure was solved from 1705 independent reflections with I > σ(I) and refined to R1 = 0.0489. Infrared and Raman spectra of the complex were recorded and are briefly discussed. Its thermal behaviour was investigated by thermogravimetry and differential thermal analysis. |
| format |
Articulo Articulo |
| author |
Tarulli, Susana H. Quinzani, Oscar V. Piro, Oscar Enrique Baran, Enrique José Castellano, Eduardo E. |
| author_facet |
Tarulli, Susana H. Quinzani, Oscar V. Piro, Oscar Enrique Baran, Enrique José Castellano, Eduardo E. |
| author_sort |
Tarulli, Susana H. |
| title |
Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II) |
| title_short |
Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II) |
| title_full |
Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II) |
| title_fullStr |
Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II) |
| title_full_unstemmed |
Structural, Spectroscopic, and Thermal Behaviour of Bis-(thiosaccharinate)- aqua-cadmium(II) |
| title_sort |
structural, spectroscopic, and thermal behaviour of bis-(thiosaccharinate)- aqua-cadmium(ii) |
| publishDate |
2001 |
| url |
http://sedici.unlp.edu.ar/handle/10915/138186 |
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