A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate
The title compound, catena-poly[[tetrakis(μ-decanoato-κ<sup>2</sup>O:O′)diruthenium(II,III)(Ru—Ru)]-μ-octanesulfonato-κ2O:O′], [Ru<sub>2</sub>(C<sub>10</sub>H<sub>19</sub>O<sub>2</sub>)<sub>4</sub>(C<sub>8</sub>H<...
| Autores principales: | , , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2002
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/126412 http://scripts.iucr.org/cgi-bin/paper?S0108270101021540 |
| Aporte de: |
| id |
I19-R120-10915-126412 |
|---|---|
| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Ciencias Exactas Química octanesulfonate diruthenium tetradecanoate ruthenium |
| spellingShingle |
Ciencias Exactas Química octanesulfonate diruthenium tetradecanoate ruthenium Zelcer, Andrés Chaia, Zulema D. Cukiernik, Fabio D. Castellano, Eduardo Ernesto Piro, Oscar Enrique A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| topic_facet |
Ciencias Exactas Química octanesulfonate diruthenium tetradecanoate ruthenium |
| description |
The title compound, catena-poly[[tetrakis(μ-decanoato-κ<sup>2</sup>O:O′)diruthenium(II,III)(Ru—Ru)]-μ-octanesulfonato-κ2O:O′], [Ru<sub>2</sub>(C<sub>10</sub>H<sub>19</sub>O<sub>2</sub>)<sub>4</sub>(C<sub>8</sub>H<sub>17</sub>O<sub>3</sub>S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains. |
| format |
Articulo Articulo |
| author |
Zelcer, Andrés Chaia, Zulema D. Cukiernik, Fabio D. Castellano, Eduardo Ernesto Piro, Oscar Enrique |
| author_facet |
Zelcer, Andrés Chaia, Zulema D. Cukiernik, Fabio D. Castellano, Eduardo Ernesto Piro, Oscar Enrique |
| author_sort |
Zelcer, Andrés |
| title |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_short |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_full |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_fullStr |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_full_unstemmed |
A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate |
| title_sort |
liquid crystal derived from ruthenium(ii,iii) and a long-chain carboxylate |
| publishDate |
2002 |
| url |
http://sedici.unlp.edu.ar/handle/10915/126412 http://scripts.iucr.org/cgi-bin/paper?S0108270101021540 |
| work_keys_str_mv |
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| bdutipo_str |
Repositorios |
| _version_ |
1764820450632794113 |