Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers

The molecular architecture of polymers is a crucial feature in the moment of think the relationship between properties and applications. The same polymer can present important differences according to its architecture and leads to different possible applications. In this paper, we describe the well...

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Detalles Bibliográficos
Autores principales:	Ríos Valer, Gabriel, Díaz, Gisela, Giussi, Juan Martín, Ceolín, Marcelo Raúl
Formato:	Articulo
Lenguaje:	Inglés
Publicado:	2019
Materias:	Química Star-shaped hyperbranched copolymers with different generation levels Thermal characterization Solution properties
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/126130
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

id	I19-R120-10915-126130
record_format	dspace
institution	Universidad Nacional de La Plata
institution_str	I-19
repository_str	R-120
collection	SEDICI (UNLP)
language	Inglés
topic	Química Star-shaped hyperbranched copolymers with different generation levels Thermal characterization Solution properties
spellingShingle	Química Star-shaped hyperbranched copolymers with different generation levels Thermal characterization Solution properties Ríos Valer, Gabriel Díaz, Gisela Giussi, Juan Martín Ceolín, Marcelo Raúl Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers
topic_facet	Química Star-shaped hyperbranched copolymers with different generation levels Thermal characterization Solution properties
description	The molecular architecture of polymers is a crucial feature in the moment of think the relationship between properties and applications. The same polymer can present important differences according to its architecture and leads to different possible applications. In this paper, we describe the well preparation of hyperbranched copolymers based on bis (HydroxylMethyl) propionic acid polyester (MPA). The co-monomers introduced via atom transfer radical polymerization were methyl methacrylate (MMA) and styrene (St). In order to study the effect of confinement, linear PMMA and PSt have been prepared, and moreover different levels of branching of each polymer were prepared. The synthesised star PMPA-PMMA and PMPA-PSt copolymers have been characterized and identified by infrared spectroscopy and nuclear magnetic resonance spectroscopy. Thermal transitions in solid state were studied using differential scanning calorimetry, and the thermal stability was evaluated by thermogravimetric analysis. Finally, solution properties have been evaluated thought Dynamic Light Scattering. Our results, obtained by a meticulous and systematic comparative study, showed a clear tendency between architectural level and thermal properties. Moreover, properties in solution revealed interesting response due to the modification of solvent nature.
format	Articulo Articulo
author	Ríos Valer, Gabriel Díaz, Gisela Giussi, Juan Martín Ceolín, Marcelo Raúl
author_facet	Ríos Valer, Gabriel Díaz, Gisela Giussi, Juan Martín Ceolín, Marcelo Raúl
author_sort	Ríos Valer, Gabriel
title	Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers
title_short	Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers
title_full	Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers
title_fullStr	Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers
title_full_unstemmed	Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers
title_sort	architecture - behaviour - properties relationship in star-shaped mpa-pmma and mpa-ps hyper-branched copolymers
publishDate	2019
url	http://sedici.unlp.edu.ar/handle/10915/126130
work_keys_str_mv	AT riosvalergabriel architecturebehaviourpropertiesrelationshipinstarshapedmpapmmaandmpapshyperbranchedcopolymers AT diazgisela architecturebehaviourpropertiesrelationshipinstarshapedmpapmmaandmpapshyperbranchedcopolymers AT giussijuanmartin architecturebehaviourpropertiesrelationshipinstarshapedmpapmmaandmpapshyperbranchedcopolymers AT ceolinmarceloraul architecturebehaviourpropertiesrelationshipinstarshapedmpapmmaandmpapshyperbranchedcopolymers
bdutipo_str	Repositorios
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Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers

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