On the Hydrides of B, C, N, O and F
This paper reports a productive discussion of bonding principles in the non-metallic 2nd row hydrides. It suggests the inversion of a bonding character, potentially from hydrides of B & C, which may display unsaturation and electronic deficiency accompanied by electronic delocalization in 1D or...
Guardado en:
| Autores principales: | , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2011
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/124076 |
| Aporte de: |
| id |
I19-R120-10915-124076 |
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| record_format |
dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Química Delocalization in 1D-2D & 3D Hydrides H-bonding Resonance |
| spellingShingle |
Química Delocalization in 1D-2D & 3D Hydrides H-bonding Resonance Bucknum, Michael J. Castro, Eduardo Alberto On the Hydrides of B, C, N, O and F |
| topic_facet |
Química Delocalization in 1D-2D & 3D Hydrides H-bonding Resonance |
| description |
This paper reports a productive discussion of bonding principles in the non-metallic 2nd row hydrides. It suggests the inversion of a bonding character, potentially from hydrides of B & C, which may display unsaturation and electronic deficiency accompanied by electronic delocalization in 1D or 2D or 3D. Contrasted with the opposite possibility, within the finite number of hydrides of N, O and F, that display apparently extensive H-bonding and subsequently proton delocalization in 1D and 2D (in HF & ice polymorphs, respectively), and now potentially in 3D in a corresponding hydride of N called Rice's blue material, or perhaps polyimidogen. Where polyimidogen is a crystalline NH lattice that is a polymorph of the ammonium azide structure-type thus. |
| format |
Articulo Articulo |
| author |
Bucknum, Michael J. Castro, Eduardo Alberto |
| author_facet |
Bucknum, Michael J. Castro, Eduardo Alberto |
| author_sort |
Bucknum, Michael J. |
| title |
On the Hydrides of B, C, N, O and F |
| title_short |
On the Hydrides of B, C, N, O and F |
| title_full |
On the Hydrides of B, C, N, O and F |
| title_fullStr |
On the Hydrides of B, C, N, O and F |
| title_full_unstemmed |
On the Hydrides of B, C, N, O and F |
| title_sort |
on the hydrides of b, c, n, o and f |
| publishDate |
2011 |
| url |
http://sedici.unlp.edu.ar/handle/10915/124076 |
| work_keys_str_mv |
AT bucknummichaelj onthehydridesofbcnoandf AT castroeduardoalberto onthehydridesofbcnoandf |
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Repositorios |
| _version_ |
1764820450751283201 |