Trans-membrane fluorescence enhancement by carbon dots: ionic interactions and energy transfer

We report on trans-membrane interactions between blue-emitting carbon dots (CDs) and fluorescein. Hydrophobic CDs with a positive surface charge are embedded as-synthesized in the lipophilic sheet of the bilayer membrane of large synthetic phospholipid vesicles. The vesicles are prepared by mixing D...

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Autores principales: Pritzl, Stefanie D., Pschunder, Fernando, Ehrat, Florian, Bhattacharyya, Santanu, Lohmüller, Theobald, Huergo, María Ana Cristina, Feldmann, Jochen
Formato: Articulo
Lenguaje:Inglés
Publicado: 2019
Materias:
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/123991
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id I19-R120-10915-123991
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Membrane sensing
Carbon dots
Ionic interactions
Lipid bilayer membranes
Trans-membrane energy transfer
spellingShingle Química
Membrane sensing
Carbon dots
Ionic interactions
Lipid bilayer membranes
Trans-membrane energy transfer
Pritzl, Stefanie D.
Pschunder, Fernando
Ehrat, Florian
Bhattacharyya, Santanu
Lohmüller, Theobald
Huergo, María Ana Cristina
Feldmann, Jochen
Trans-membrane fluorescence enhancement by carbon dots: ionic interactions and energy transfer
topic_facet Química
Membrane sensing
Carbon dots
Ionic interactions
Lipid bilayer membranes
Trans-membrane energy transfer
description We report on trans-membrane interactions between blue-emitting carbon dots (CDs) and fluorescein. Hydrophobic CDs with a positive surface charge are embedded as-synthesized in the lipophilic sheet of the bilayer membrane of large synthetic phospholipid vesicles. The vesicles are prepared by mixing DOPC phospholipids and lipid molecules that contain anionic fluorescein attached to their hydrophilic head. Due to attractive electrostatic interactions, the CDs and fluorescein conjoin within the vesicle membrane, which leads to photoluminescence enhancement of fluorescein and facilitates trans-membrane energy transfer between the CDs and the dye.
format Articulo
Articulo
author Pritzl, Stefanie D.
Pschunder, Fernando
Ehrat, Florian
Bhattacharyya, Santanu
Lohmüller, Theobald
Huergo, María Ana Cristina
Feldmann, Jochen
author_facet Pritzl, Stefanie D.
Pschunder, Fernando
Ehrat, Florian
Bhattacharyya, Santanu
Lohmüller, Theobald
Huergo, María Ana Cristina
Feldmann, Jochen
author_sort Pritzl, Stefanie D.
title Trans-membrane fluorescence enhancement by carbon dots: ionic interactions and energy transfer
title_short Trans-membrane fluorescence enhancement by carbon dots: ionic interactions and energy transfer
title_full Trans-membrane fluorescence enhancement by carbon dots: ionic interactions and energy transfer
title_fullStr Trans-membrane fluorescence enhancement by carbon dots: ionic interactions and energy transfer
title_full_unstemmed Trans-membrane fluorescence enhancement by carbon dots: ionic interactions and energy transfer
title_sort trans-membrane fluorescence enhancement by carbon dots: ionic interactions and energy transfer
publishDate 2019
url http://sedici.unlp.edu.ar/handle/10915/123991
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