Dolomite-zirconia reaction sintered bonded coarse magnesia ceramics: effect of the bonding proportion

Refractory ceramic materials were manufactured, mainly composed of magnesia grains (coarse and medium fraction) and CaZrO₃/MgO as a binding phase produced from the reaction sintering between CaMg(CO₃)₂ (dolomite) and m-ZrO₂ (monoclinic zirconia), which constituted the finer fraction. Different relat...

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Autores principales: Booth, Raúl Fernando Nicolás, Stábile, Franco Matías, Bruni, Yésica Lorena, Gauna, Matías Roberto, Rendtorff Birrer, Nicolás Maximiliano
Formato: Articulo
Lenguaje:Español
Publicado: 2021
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/123685
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id I19-R120-10915-123685
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Español
topic Ciencias Exactas
Química
Ingeniería Química
magnesia
calcium zirconate
refractory ceramics
spellingShingle Ciencias Exactas
Química
Ingeniería Química
magnesia
calcium zirconate
refractory ceramics
Booth, Raúl Fernando Nicolás
Stábile, Franco Matías
Bruni, Yésica Lorena
Gauna, Matías Roberto
Rendtorff Birrer, Nicolás Maximiliano
Dolomite-zirconia reaction sintered bonded coarse magnesia ceramics: effect of the bonding proportion
topic_facet Ciencias Exactas
Química
Ingeniería Química
magnesia
calcium zirconate
refractory ceramics
description Refractory ceramic materials were manufactured, mainly composed of magnesia grains (coarse and medium fraction) and CaZrO₃/MgO as a binding phase produced from the reaction sintering between CaMg(CO₃)₂ (dolomite) and m-ZrO₂ (monoclinic zirconia), which constituted the finer fraction. Different relationships between the proportion and the size of the different aggregates were studied. The microstructure of the materials was characterized in terms of density, crystalline phases, grain phase distribution, and morphology. A combination of X-ray diffraction analysis and scanning electron microscopy with microanalysis was used. The mechanical behavior was determined in terms of the room temperature dynamic Young’s modulus and the 3-point bending modulus of rupture (MOR) at room temperature. All the materials remained with porosities above 30%. The microstructure developed was similar between the sintered materials, characterized with MgO coarse grains bonded by CaZrO₃/c-ZrO₂ phases, and dispersed irregularly shaped pores. The MOR was directly related to the finer fraction content in the composition, where a higher quantity of finer fraction resulted in a higher MOR.
format Articulo
Articulo
author Booth, Raúl Fernando Nicolás
Stábile, Franco Matías
Bruni, Yésica Lorena
Gauna, Matías Roberto
Rendtorff Birrer, Nicolás Maximiliano
author_facet Booth, Raúl Fernando Nicolás
Stábile, Franco Matías
Bruni, Yésica Lorena
Gauna, Matías Roberto
Rendtorff Birrer, Nicolás Maximiliano
author_sort Booth, Raúl Fernando Nicolás
title Dolomite-zirconia reaction sintered bonded coarse magnesia ceramics: effect of the bonding proportion
title_short Dolomite-zirconia reaction sintered bonded coarse magnesia ceramics: effect of the bonding proportion
title_full Dolomite-zirconia reaction sintered bonded coarse magnesia ceramics: effect of the bonding proportion
title_fullStr Dolomite-zirconia reaction sintered bonded coarse magnesia ceramics: effect of the bonding proportion
title_full_unstemmed Dolomite-zirconia reaction sintered bonded coarse magnesia ceramics: effect of the bonding proportion
title_sort dolomite-zirconia reaction sintered bonded coarse magnesia ceramics: effect of the bonding proportion
publishDate 2021
url http://sedici.unlp.edu.ar/handle/10915/123685
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